(a) Interpretation: All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile + NO 2 are to be drawn. The resonance structures are to be labeled as stable or unstable. Concept introduction: Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

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Answer 1

Question

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

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Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. LOCH3 LOCH3 HNO3 / CH3CO₂H O₂N • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. ● In cases where there is more than one answer, just draw one.

A benzene ring alters the reactivity of a neighboring group in the so-called “benzylic” position, similarly to how a double bond alters the reactivity of groups in the “allylic” position. Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates. a) Use resonance structures to show the delocalization of the positive charge, negative charge, and unpaired electron of the benzyl cation, anion, and radical.

Draw a structural formula for the substitution product of the reaction shown below. H3C H Br Na' acetone • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one stereoisomer of product is formed, draw both. Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms. C P opy aste [F ChemDoodle

Answer 2

Question

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

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Answer 3

Question

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

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Answer 4

Question

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

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Answer 5

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

Answer 6

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Answer 7

Chapter 18, Problem 18.19P

Interpretation Introduction

(a)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Answer 8

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Answer 9

Interpretation Introduction

(b)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

Answer 10

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

Answer 11

Interpretation Introduction

(c)

Interpretation:

All resonance structures for the carbocation of given compound formed by ortho attack of the electrophile +NO2 are to be drawn. The resonance structures are to be labeled as stable or unstable.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - What acid chloride would be needed to prepare each...Ch. 18 - Prob. 18.7P Ch. 18 - Draw a stepwise mechanism for the following...Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains that all resonance structures for the carbocation of given compound formed by ortho attack of the electrophile are to be drawn and labeled as stable or unstable.

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