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Concept explainers
(a)
Interpretation:The synthesis of given compound from benzene is to be predicted.
Concept introduction: The substitution reaction involves the replacement of one
(b)
Interpretation: The synthesis of given compound from benzene is to be predicted.
Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.
(c)
Interpretation: The synthesis of given compound from benzene is to be predicted.
Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.
(d)
Interpretation: The synthesis of given compound from benzene is to be predicted.
Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.
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Chapter 18 Solutions
ORGANIC CHEMISTRY
- Give the IUPAC name for each compound. CH3 CH2CH3 Br a. PHCH(CH3)2 b. С. d.arrow_forwardb. d. a. a 6. Draw the organic product formed for each reaction. COOH COOH A [1] LDA [2] CH3CH₂l [1] Br₂. CH3CO₂H [2] Li₂CO3. LiBr. DMF 12 (excess) TOH CN NaH Br₂ (excess) TOH + CHI3arrow_forwardChemistry One step synthesis: derive a way to accomplish the transformations shown. a. b. Br OH olt C. o CHz Cltz CH3arrow_forward
- Give the structure corresponding to each name. a. 7,7-dimethyl-4-octanol b. 5-methyl-4-propyl-3-heptanol c. 2-tert-butyl-3-methylcyclohexanol d. trans-1,2-cyclohexanediolarrow_forwardProvide reagents and reaction conditions for each steparrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forward
- 1. Complete the following reactions. a. b. C. N HIN 1. LiAlH4 2. H₂O* 1. NaAlH4 2. H₂O* 1. LiAlH4 2. H₂O*arrow_forwardWhich is the major organic product of this reaction? A. B. 4 ОА O OB O C COD AICI3 benzene C. D.arrow_forward1. Draw the products in each reaction. a. H b. CH3-C-CH₂CH3 CI -OH K+ -OC(CH3)3 CH₂CH3 a Xa C. d. CH₂CH₂OH CH3CH₂O™arrow_forward
- 17. What is the missing reagent in the reaction below? aq. HCI A. CH2(COOE1)2, NaOEt C. CH2(COOE1)2, HOAC B. CH3CO2Et, NaOEt D. CH3CO,Et, HOAC 18. In several reactions of carhonyl compounds that we have studied, the reaction proceeds by carrow_forwardW X Select reagent W and Y 1 HNO3 H₂SO4 2 CH3C1₂ AICI 3 3 Cl₂, FeCl3 ) 4 503, H₂SO4 NO₂ S0₂tarrow_forwardcompound a HC=CH a. b. compound f Reagents HCI HBr H₂O, H₂SO4 C. d. Br₂ e. Cl₂ r compound d compound j compound i n compound h compound c compound b n HC=CH m. n. O. compound g compound e HC=CH 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 p. H₂SO4, HgSO4 q. (sia)₂BH then H₂O₂, NaOH Prarrow_forward
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