Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 19, Problem 88AE
Interpretation Introduction
Interpretation: The precipitation of
Concept Introduction:
A metal complex can be show as
Usually
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About the Alfred warner theory of complexation charge (all are correct except
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1-the neutralized ionic complex with a counter ion leading to a non ionizable complex is known to have a secondary
2- the ionized complexes of cationic or anionic charge is known to be of primary or principle valence
3- the complex geometry/ shape is not related to the coordination number
4- each metal have a number of secondary valencies known as coordination number
A complex is written as NiBr2 . 6 NH3. (a) What is the oxidationstate of the Ni atom in this complex? (b) What isthe likely coordination number for the complex? (c) Ifthe complex is treated with excess AgNO3(aq), how manymoles of AgBr will precipitate per mole of complex?
Describe the makeup of a complex ion, including the natureof the ligands and their interaction with the central metal ion.Explain how a complex ion can be positive or negative and howit occurs as part of a neutral coordination compound.
Chapter 19 Solutions
Chemical Principles
Ch. 19 - Prob. 1DQCh. 19 - Prob. 2DQCh. 19 - Prob. 3DQCh. 19 - Prob. 4DQCh. 19 - Prob. 5DQCh. 19 - Prob. 6ECh. 19 - Prob. 7ECh. 19 - What two first-row transition metals have...Ch. 19 - Prob. 9ECh. 19 - Prob. 10E
Ch. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - Prob. 15ECh. 19 - Define each of the following terms. a....Ch. 19 - Prob. 17ECh. 19 - When a metal ion has a coordination number of 2,...Ch. 19 - The compound cisplatin, Pt(NH3)2Cl2 , has been...Ch. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 25ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - For the process Co(NH3)5Cl2++Cl2Co(NH3)4Cl2++NH3...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Consider the complex ions...Ch. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - How many unpaired electrons are in the following...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65ECh. 19 - Prob. 66ECh. 19 - Prob. 67ECh. 19 - Prob. 68ECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 88AECh. 19 - Prob. 89AECh. 19 - Prob. 90AECh. 19 - Prob. 91AECh. 19 - Prob. 92AECh. 19 - Prob. 93AECh. 19 - Prob. 94AECh. 19 - Prob. 95AECh. 19 - Prob. 96AECh. 19 - Prob. 97CPCh. 19 - Prob. 98CPCh. 19 - Prob. 99CPCh. 19 - Prob. 100CPCh. 19 - Prob. 101CPCh. 19 - Prob. 102CPCh. 19 - Prob. 103CPCh. 19 - Prob. 104CP
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- For the aqueous [PbC1]2- complex K=2.5 × 10^15 at 25 °CSuppose equal volumes of 0.0014 M Pb(NO), solution and 0.20 M KCI solution are mixed. Calculate the equilibrium molarity of aqueous Pb2+Round vour answer to 2 sianificant digitsarrow_forward(a) A compound with formula RuCl3 . 5 H2O is dissolved inwater, forming a solution that is approximately the samecolor as the solid. Immediately after forming the solution,the addition of excess AgNO3(aq) forms 2 mol of solid AgClper mole of complex. Write the formula for the compound,showing which ligands are likely to be present in the coordinationsphere. (b) After a solution of RuCl3 . 5 H2O hasstood for about a year, addition of AgNO3(aq) precipitates 3mol of AgCl per mole of complex. What has happened inthe ensuing time?arrow_forwardThe actinides Pa, U, and Np form a series of complex ions,such as the anion in the compound Na₃[UF₈] , in which the cen-tral metal ion has an unusual geometry and oxidation state. In thecrystal structure, the complex ion can be pictured as resultingfrom interpenetration of simple cubic arrays of uranium and fluo-ride ions. (a) What is the coordination number of the metal ion inthe complex ion? (b) What is the oxidation state of uranium inthe compound? (c) Sketch the complex ion.arrow_forward
- A sample contains Pb2+, Mg2+ and Zn2+. 0.4085 g of the sample is weighed and dissolved. Once dissolved it is with cyanide to form a complex and mask the zinc (Zn2++ 4 CN-→ Zn (CN)4 2-). The Pb2+ and Mg2+ in the solution are titrated with 42.22 mL of EDTA 0.02604 M. Then the Pb complex is treated with another organic ligand that masks Pb and releases EDTA, which is titrated with 19.35 mL of a Mg2+ 0.007657 M solution. For finalize formaldehyde is added to unmask the Zn2+(Zn (CN)4 2- + 4 HCHO + 4 H2O → Zn2+ + 4 HOCH2CN + 4 OH-). The liberated zinc is titrated with EDTA 0.02064 M consuming 28.63 mL. (Data: Pat Pb, 207.22; Pat Mg, 24.31; Pat Zn, 65.4). Find the percentage of the three metals in the sample.arrow_forwardIf the complex is treated with excess AgNO3(aq)AgNO3(aq), how many moles of AgClAgCl will precipitate per mole of CrCl3⋅6H2OCrCl3⋅6H2O dissolved in solution?arrow_forwardWhat following factor affect the stability constant of metal complexes? equilibrium concentration of the free metal ion temperature analytical concentration of the metal ion pH of the solutionarrow_forward
- A redox reaction between two complexes is activated by adding a small concentration of pyrazine, but not changed by adding pyridine. Give a brief explanation.arrow_forwardThe values for lmax for complex A and B are 512 nm and 650 nm respectively. A has the structure [Co(NH3)4CO3]NO3 while B is [Co(NH3)4Cl2]Cl. Explain this data based on the Crystal Field Theory UV-visible spectroscopy provides information about cobalt(III) complexes. A blue cobalt complex has molar absorbtivity of 125 Lmol-1cm-1. Is the complex octahedral or tetrahedral? Justify your answer and explain the colour of the complex.arrow_forwardCrystals of hydrated chromium(III) chloride are green,have an empirical formula of CrCl3 . 6 H2O, and are highlysoluble, (a) Write the complex ion that exists in this compound.(b) If the complex is treated with excess AgNO3(aq),how many moles of AgCl will precipitate per mole ofCrCl3 . 6 H2O dissolved in solution? (c) Crystals of anhydrouschromium(III) chloride are violet and insoluble inaqueous solution. The coordination geometry of chromiumin these crystals is octahedral, as is almost always thecase for Cr3+. How can this be the case if the ratio of Cr toCl is not 1:6?arrow_forward
- A complex is written as NiBr2.6NH3 What is the oxidation state of Ni atom in this complex? What is the likely coordination number for the complex? If the complex is treated with excess AgNO3 (aq), how many moles of AgBr will precipate per mole of complex?arrow_forwardWhen MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately for each mole of MCl4(NH3)2. Give the coordination number of M in the complex.arrow_forwardIf given the choice of a complexometric titrant among the choices below, which would be the best option, and why? Unidentate ligands, because they form more stable complexes with metal ions Bidentate ligands, because they form more stable complexes with metal ions Tridentate ligands, because they form more stable complexes with metal ions Hexadentate ligands, because they form more stable complexes with metal ionsarrow_forward
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