Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 2, Problem 21P
  1. Draw resonance structure for the CO, choosing only those that you think contribute significantly to the bonding.

  2. Figure 2.15a shows an MO diagram for CO. Two MOs are illustrated by schematic representations. Draw similar diagrams for the remaining six MOs.

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Look up the energies for the bonds in CO and N2. Although the bond in CO is stronger, CO is considerably more reactive than N2. Give a possible explanation.
Please also explain how the negative charge affects the MO and AO numbers.
(b) Classify O2 and N2 as either paramagnetic or diamagnetic. Explain your answer by completing the orbitals in the given MO energy level diagrams above and referring to the electronic structure of these two molecules.

Chapter 2 Solutions

Inorganic Chemistry

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Linear Combination of Atomic Orbitals LCAO; Author: Edmerls;https://www.youtube.com/watch?v=nq1zwrAIr4c;License: Standard YouTube License, CC-BY
Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY