A stepwise mechanism for the given transformation is to be stated. Concept introduction: Grignard reagents react with derivatives of carboxylic esters RCOZ (where, Z = Cl or OR ' ) to yield ketones or 3 ο alcohols. The reaction utilizes two equivalents of Grignard reagent. However, when Z = OR ' ; R = OR ' , the reaction utilizes three equivalents of Grignard reagent to yield tertiary alcohol.

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.53P

Interpretation Introduction

Interpretation: A stepwise mechanism for the given transformation is to be stated.

Concept introduction: Grignard reagents react with derivatives of carboxylic esters RCOZ (where, Z=Cl or OR') to yield ketones or 3ο alcohols. The reaction utilizes two equivalents of Grignard reagent. However, when Z=OR'; R=OR', the reaction utilizes three equivalents of Grignard reagent to yield tertiary alcohol.

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Propose two different methods to synthesize oct-1 -en-3-ol [CH3(CH2)4CH(OH)CH = CH2] using a Grignard reagent and a carbonyl compound. Oct-1-en-3-ol is commonly called matsutake alcohol because it was first isolated from the Japanese matsutake mushroom.

Propose two different methods to synthesize oct-1 -en-3-ol [CH3(CH2)4CH(OH)CH = CH2] using a Grignard reagent and a carbonyl compound. Oct-1-en-3-ol is commonly called matsutake alcohol because it was rst isolated from the Japanese matsutake mushroom.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.53P

Interpretation Introduction

Interpretation: A stepwise mechanism for the given transformation is to be stated.

Concept introduction: Grignard reagents react with derivatives of carboxylic esters RCOZ (where, Z=Cl or OR') to yield ketones or 3ο alcohols. The reaction utilizes two equivalents of Grignard reagent. However, when Z=OR'; R=OR', the reaction utilizes three equivalents of Grignard reagent to yield tertiary alcohol.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.53P

Interpretation Introduction

Interpretation: A stepwise mechanism for the given transformation is to be stated.

Concept introduction: Grignard reagents react with derivatives of carboxylic esters RCOZ (where, Z=Cl or OR') to yield ketones or 3ο alcohols. The reaction utilizes two equivalents of Grignard reagent. However, when Z=OR'; R=OR', the reaction utilizes three equivalents of Grignard reagent to yield tertiary alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.53P

Interpretation Introduction