Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 20, Problem 20.13P
Interpretation Introduction
(a)
Interpretation: The amide which forms the given amine on the treatment with
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in
Interpretation Introduction
(b)
Interpretation: The amide which forms the given amine on the treatment with
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of amides to amines.
Interpretation Introduction
(c)
Interpretation: The amide which forms the given amine on the treatment with
Concept introduction: Lithium aluminum hydride is a strong reducing agent. It is an inorganic compound which is used as a reducing agent in organic synthesis. It is used for the conversion of amides to amines.
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Chapter 20 Solutions
Organic Chemistry
Ch. 20 - Prob. 20.1PCh. 20 - Which carbonyl groups in the anticancer drug taxol...Ch. 20 - Prob. 20.3PCh. 20 - Problem 20.4 What alcohol is formed when each...Ch. 20 - Problem 20.5 What aldehyde or ketone is needed to...Ch. 20 - Prob. 20.6PCh. 20 - Problem 20.7 Draw the products formed when is...Ch. 20 - Problem 20.8 Draw the products formed (including...Ch. 20 - Prob. 20.9PCh. 20 - Problem 20.10 Draw a stepwise mechanism for the...
Ch. 20 - Prob. 20.11PCh. 20 - Problem 20.12 Draw the products formed from ...Ch. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Problem-20.16 Review the oxidation reactions using...Ch. 20 - Problem-20.17 Write the step(s) needed to convert ...Ch. 20 - Problem-20.18 Oct-1-yne reacts rapidly with ,...Ch. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Problem 20.21 Draw the product of each reaction.
...Ch. 20 - Problem 20.22 Draw the products (including...Ch. 20 - Problem 20.23 What Grignard reagent and carbonyl...Ch. 20 - Problem 20.24 Linalool (the Chapter 9 opening...Ch. 20 - Problem 20.25 What Grignard reagent and carbonyl...Ch. 20 - Prob. 20.26PCh. 20 - Draw the products formed when each compound is...Ch. 20 - Problem 20.28 What ester and Grignard reagent are...Ch. 20 - Prob. 20.29PCh. 20 - Problem 20.30 What reagent is needed to convert ...Ch. 20 - Prob. 20.31PCh. 20 - What carboxylic acid formed from each alkyl halide...Ch. 20 - Prob. 20.33PCh. 20 - Problem 20.34 Draw the product when each compound...Ch. 20 - Problem 20.35 Synthesize each compound from...Ch. 20 - Prob. 20.36PCh. 20 - 20.37 Devise a synthesis of each alcohol from...Ch. 20 - 20.38 Draw the products formed when pentanal is...Ch. 20 - 20.39 Draw the product formed when is treated...Ch. 20 - The stereochemistry of the products of reduction...Ch. 20 - Prob. 20.41PCh. 20 - 20.42 Draw the products or each reduction...Ch. 20 - Prob. 20.43PCh. 20 - 20.44 Draw all stereoisomers formed in each...Ch. 20 - Prob. 20.45PCh. 20 - 20.46 Treatment of ketone A with ethynylithium...Ch. 20 - 20.47 Explain why metal hydride reduction gives an...Ch. 20 - Prob. 20.48PCh. 20 - 20.49 Identify the lettered compounds in the...Ch. 20 - Prob. 20.50PCh. 20 - 20.51 Draw a stepwise mechanism for the following...Ch. 20 - 20.52 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.53PCh. 20 - 20.54 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.55PCh. 20 - Prob. 20.56PCh. 20 - 20.57 What ester and Grignard reagent are needed...Ch. 20 - 20.58 What organolithium reagent and carbonyl...Ch. 20 - 20.59 What epoxide and organometallic reagent are...Ch. 20 - Prob. 20.60PCh. 20 - 20.61 Propose two different methods to synthesize...Ch. 20 - 20.62 Synthesize each compound from cyclohexanol...Ch. 20 - 20.63 Convert propan-2-ol into each compound....Ch. 20 - 20.64 Convert benzene into each compound. You may...Ch. 20 - 20.65 Design a synthesis of each compound from...Ch. 20 - 20.66 Synthesize each compound from the given...Ch. 20 - Prob. 20.67PCh. 20 - Prob. 20.68PCh. 20 - 20.69 An unknown compound A (molecular formula )...Ch. 20 - 20.70 Treatment of compound C (molecular formula )...Ch. 20 - 20.71 Treatment of compound E (molecular formula )...Ch. 20 - 20.72 Reaction of butanenitrile () with methyl...Ch. 20 - 20.73 Treatment of isobutene with forms a...Ch. 20 - 20.74 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.75PCh. 20 - 20.76 Lithium tri-sec-butylborohydride, also known...Ch. 20 - Prob. 20.77PCh. 20 - Prob. 20.78PCh. 20 - Prob. 20.79PCh. 20 - 20.80 Draw a stepwise mechanism for the following...Ch. 20 - Prob. 20.81P
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Similar questions
- Give each of the following amines an IUPAC name. a. b. c.arrow_forwardWhat is the IUPAC name of the following compound? a) 2-methyl-3-amino-1-cyclopentanone b) 3-amine-2-methyl-1-cyclopentanone c) 2-methyl-3-aminocyclopentanone d) 3-amino-2-methylcyclopentanonearrow_forwardAromatic amines are _________ neutral because of the polarity are unique as they do not behave like any of the other amines acidic, but stronger than the aliphatic amines basic, but weaker than aliphatic aminesarrow_forward
- Reductive amination of carbonyl compounds produces the same kinds of products as does the reaction of amines and alkyl halides True or Falsearrow_forwardWhat products are formed when each amide is hydrolyzed with water and HCl?arrow_forwardN-p-hydroxyphenylethanamide is commonly known as a. acetaminophen b. acetamide c. acetanilide d. formamide High molar mass amines have __________ odor. a.strong ammoniacal b.fruity c.fishy d.obnoxious Trimethyl amine has _________ odor. a.obnoxious b.fishy c. ammoniacal d. fruityarrow_forward
- Give a systematic name for each amidearrow_forwardGive the common names for each of the following ethers ot amines (a) CH3---O--CH2CH2CH2CH3 (b) CH3CH2----O---CH2CH3 (c) CH3CH2--N---CH3 I CH3 (d) CH3CH2----N---CH3 | Harrow_forwardMany drugs are sold as their hydrochloride salts (R2NH2 + Cl−), formed by reaction of an amine (R2NH) with HCl . Question: Draw the product (a hydrochloride salt) formed by reaction ofacebutolol with HCl. Acebutolol is a β blocker used to treat high bloodpressure.arrow_forward
- The presence of amides in living organisms is beneficial due its stability which results from being the least reactive carboxylic acid derivative. True or Falsearrow_forwardDraw a structural formula for each amine and amine derivative. Q.) N,N-Dimethylanilinearrow_forward2. This term means without water. a. carbonyl b. hydroxyl c. anhydride d. carboyl 3. Compounds containing the cyano group. a. nitriles b. amides c. amines d. nitrates 4. General formula of a Grignard reagent. a. RCOX b. RCN c. RCOOH d. RMgX 5. Organic derivatives of ammonia, derived from replacing one, two or all three hydrogens of the ammonia. a. amide b. amine c. cyan d. nitro 6. Sulfur analogs of alcohols where the O in R-OH is replaced by sulfur. a. Thioesters b. Thiols c. Thioaldehydes d. Thioethers 7. General formula of alkanes. a. CnH2n b. CnH2n+2 c. CnH2n-2 d. R-OH 8. General formula of alkenes. a. CnH2n b. CnH2n+2 c. CnH2n-2 d. R-OH 9. General formula of alkynes. a. CnH2n b. CnH2n+2 c. CnH2n-2 d. R-OH 10. Which is soluble in water? a. methanol b. ethanol c. propanol d. all of the above 11. Which substance will have the highest boiling point? a. methanol b. ethanol c. propanol d. butanol 12. Which property will increase the boiling point? a. electronegativity…arrow_forward
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