Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Question
Chapter 20, Problem 92QRT
(a)
Interpretation Introduction
Interpretation:
Coordination number of the central metal ion in
(b)
Interpretation Introduction
Interpretation:
Coordination number of the central metal ion in
(c)
Interpretation Introduction
Interpretation:
Coordination number of the central metal ion in
(d)
Interpretation Introduction
Interpretation:
Coordination number of the central metal ion in
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The coordination compound that was asked was
Potassium tetrachloroaurate(III), AuCl4K.
When cobalt(II) chloride is treated, under certain condition, with the bidentate ligand, NH2CH2CH2NH2, (which can be represented by the symbol “en”), the compound [CoC12(en)2]Cl is formed.
a. What is the coordination number of cobalt in this compound?
What is the oxidation state of the metal centre in the [Cr(CO3)3(C6H6)] complex?
Chapter 20 Solutions
Chemistry: The Molecular Science
Ch. 20.1 - Use partial atomic orbital box diagrams to explain...Ch. 20.1 - Prob. 20.1ECh. 20.1 - Prob. 20.2ECh. 20.2 - Prob. 20.2PSPCh. 20.2 - Prob. 20.3PSPCh. 20.2 - Prob. 20.3ECh. 20.3 - Explain how zinc and lead could be separated from...Ch. 20.3 - Prob. 20.4ECh. 20.4 - Prob. 20.5ECh. 20.5 - Use data from Appendix J to calculate the enthalpy...
Ch. 20.5 - Use Le Chatelier’s principle to explain how the...Ch. 20.5 - At what pH does Ecell = 0.00 V for the reduction...Ch. 20.6 - Prob. 20.6PSPCh. 20.6 - Prob. 20.8CECh. 20.6 - (a) Name this coordination compound:...Ch. 20.6 - Prob. 20.9CECh. 20.6 - Prob. 20.8PSPCh. 20.6 - Prob. 20.10CECh. 20.6 - Prob. 20.11CECh. 20.6 - Prob. 20.9PSPCh. 20.6 - Prob. 20.12ECh. 20.7 - Prob. 20.10PSPCh. 20.7 - Prob. 20.13CECh. 20.7 - Prob. 20.14CECh. 20 - Prob. 1QRTCh. 20 - Prob. 2QRTCh. 20 - Prob. 3QRTCh. 20 - Prob. 4QRTCh. 20 - Prob. 5QRTCh. 20 - Prob. 6QRTCh. 20 - Prob. 7QRTCh. 20 - Prob. 8QRTCh. 20 - Prob. 9QRTCh. 20 - Prob. 10QRTCh. 20 - Prob. 11QRTCh. 20 - Prob. 12QRTCh. 20 - Prob. 13QRTCh. 20 - Prob. 14QRTCh. 20 - Prob. 15QRTCh. 20 - Which Period 4 transition-metal ions are...Ch. 20 - Prob. 17QRTCh. 20 - Prob. 18QRTCh. 20 - Prob. 19QRTCh. 20 - Prob. 20QRTCh. 20 - Prob. 21QRTCh. 20 - Prob. 22QRTCh. 20 - Prob. 23QRTCh. 20 - Prob. 24QRTCh. 20 - Prob. 25QRTCh. 20 - Prob. 26QRTCh. 20 - Prob. 27QRTCh. 20 - Prob. 28QRTCh. 20 - Prob. 29QRTCh. 20 - Prob. 30QRTCh. 20 - Prob. 31QRTCh. 20 - Prob. 32QRTCh. 20 - Prob. 33QRTCh. 20 - Prob. 34QRTCh. 20 - Prob. 35QRTCh. 20 - Prob. 36QRTCh. 20 - Prob. 37QRTCh. 20 - Prob. 38QRTCh. 20 - Prob. 39QRTCh. 20 - Prob. 40QRTCh. 20 - Prob. 41QRTCh. 20 - Prob. 42QRTCh. 20 - Prob. 43QRTCh. 20 - Prob. 44QRTCh. 20 - Prob. 45QRTCh. 20 - Prob. 46QRTCh. 20 - Prob. 47QRTCh. 20 - Prob. 48QRTCh. 20 - Prob. 49QRTCh. 20 - Prob. 50QRTCh. 20 - Prob. 51QRTCh. 20 - Prob. 52QRTCh. 20 - Give the charge on the central metal ion in each...Ch. 20 - Prob. 54QRTCh. 20 - Prob. 55QRTCh. 20 - Classify each ligand as monodentate, bidentate,...Ch. 20 - Prob. 57QRTCh. 20 - Prob. 58QRTCh. 20 - Prob. 59QRTCh. 20 - Prob. 60QRTCh. 20 - Prob. 61QRTCh. 20 - Prob. 62QRTCh. 20 - Prob. 63QRTCh. 20 - Prob. 64QRTCh. 20 - Prob. 65QRTCh. 20 - Prob. 66QRTCh. 20 - Prob. 67QRTCh. 20 - Prob. 68QRTCh. 20 - Prob. 69QRTCh. 20 - Prob. 70QRTCh. 20 - Prob. 71QRTCh. 20 - Prob. 72QRTCh. 20 - Prob. 73QRTCh. 20 - Prob. 74QRTCh. 20 - How many unpaired electrons are in the high-spin...Ch. 20 - Prob. 76QRTCh. 20 - Prob. 77QRTCh. 20 - Prob. 78QRTCh. 20 - An aqueous solution of [Rh(C2O4)3]3− is yellow....Ch. 20 - Prob. 80QRTCh. 20 - Prob. 81QRTCh. 20 - Prob. 82QRTCh. 20 - Prob. 83QRTCh. 20 - Prob. 84QRTCh. 20 - Give the electron configuration of (a) Ti3+. (b)...Ch. 20 - Prob. 86QRTCh. 20 - Prob. 87QRTCh. 20 - Prob. 88QRTCh. 20 - Prob. 89QRTCh. 20 - Prob. 90QRTCh. 20 - Prob. 91QRTCh. 20 - Prob. 92QRTCh. 20 - Prob. 93QRTCh. 20 - Prob. 94QRTCh. 20 - Prob. 95QRTCh. 20 - Prob. 96QRTCh. 20 - Prob. 97QRTCh. 20 - Prob. 98QRTCh. 20 - Prob. 99QRTCh. 20 - Prob. 100QRTCh. 20 - Prob. 101QRTCh. 20 - Prob. 103QRTCh. 20 - Prob. 104QRTCh. 20 - Prob. 105QRTCh. 20 - Prob. 106QRTCh. 20 -
Repeat the directions for Question 106 using a...Ch. 20 - Prob. 113QRTCh. 20 - Prob. 114QRTCh. 20 - Prob. 115QRTCh. 20 - Prob. 116QRTCh. 20 - Prob. 117QRTCh. 20 - Prob. 118QRTCh. 20 - Prob. 119QRTCh. 20 - Prob. 120QRTCh. 20 - The glycinate ion (gly) is H2NCH2CO2. It can act...Ch. 20 - Five-coordinate coordination complexes are known,...Ch. 20 - Prob. 123QRTCh. 20 - Prob. 124QRTCh. 20 - Two different compounds are known with the formula...Ch. 20 - Prob. 126QRT
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- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardCarbon monoxide, CO, is an important ligand in coordinationchemistry. When CO is reacted with nickel metal,the product is [Ni(CO)4], which is a toxic, pale yellow liquid.(a) What is the oxidation number for nickel in thiscompound? (b) Given that [Ni(CO)4] is a diamagneticmolecule with a tetrahedral geometry, what is the electronconfiguration of nickel in this compound? (c) Write thename for [Ni(CO)4] using the nomenclature rules for coordinationcompounds.arrow_forwardConsider the following coordination compound: [CoCl(NH3)4(H2O)]SO4- What is its formula and charge. Explain how you get the charge clearly please.arrow_forward
- The coordination complex [Cr(CO)6] forms colorless, diamagnetic crystals that melt at 90 °C. Given that [Cr(CO)6] is colorless, would you expect CO to be a weak-field or strong-field ligand?arrow_forwardAqueous solutions of [Mn(H2O)6]2+ are faint pink, so much so that they appear to be colorless, which is in contrast to other coordination complexes that we have seen to this point in the course. a) Please explain why this solution is colorless. b) If the water ligands were changed to bipyridine (bpy) ligands and you had [Mn(bpy)3]2+, would the solution still be colorless? What changes, if any, would you expect to see in the visible spectrum? If the complex would be expected to have absorptions, please note now many.arrow_forwardWhat is the valence electron number and effective atomic number of the [CrCl3 (NH3) 3] coordination compound?arrow_forward
- A coordination compound of ruthenium, [Ru(NH3)4Cl2]Cl, has shown some activity against leukemia in animal studies. Give the formula for the counter ionarrow_forwardGive 5 examples of metal coordination complexes and enumerate their importancearrow_forwardWhat is the coordination number of the central metal in [Co(en)3]Cl2 ? The en (NH2CH2CH2NH2) ligand can be classified as:____arrow_forward
- Explain the terms diamagnetic and paramagnetic NiCl2(PPh3)2 is a green paramagnetic solid, while cis Ni(SCN)2(PPh3)2 is red and diamagnetic. With the aid of crystal field diagrams, give the metal coordination! environment in both complexes. Why do they differ?arrow_forwardWhat are the coordination numbers of cobalt(III), plat-inum(II), and platinum(IV) in complexes?arrow_forwardFor the low-spin coordination compound [Fe(en)2Cl2]Cl, identify the following.(a) the oxidation number of iron(b) the coordination number for iron(c) the coordination geometry for iron(d) the number of unpaired electrons per metal atom(e) whether the complex is diamagnetic or paramagnetic(f) the number of geometricisomersarrow_forward
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