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Concept explainers
(a)
Interpretation: The reagent required to convert the given compound into butanal is to be predicted.
Concept introduction: Diisobutylaluminiumhydride(DIBAL-H) is a selective reducing agent. It readily converts esters into
(b)
Interpretation: The reagent required to convert the given compound into butanal is to be predicted.
Concept introduction: The full form of PCC is pyridinium chlorochromate. It acts as mild oxidizing agent. It oxidizes primary alcohols into aldehyde and secondary alcohol into
(c)
Interpretation: The reagent required to convert the given compound into butanal is to be predicted.
Concept introduction: A stepwise procedure of transforming an
(d)
Interpretation: The reagent required to convert the given compound into butanal is to be predicted.
Concept introduction: In presence of ozone and
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Chapter 21 Solutions
ORGANIC CHEMISTRY
- 1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forwardstructure name CH3 CH;-C= CH – CH, CH, CH, — сH, — с — сн, CH3 CH;- CH – C= CHarrow_forwardWrite a balanced equation for the combustion of each alkane: (a) CH 3CH 3; (b) (CH 3) 2CHCH 2CH 3arrow_forward
- Name these organic compounds: structure name CH, CH, — сн, — с — сн, CH2 CH, — с — сн, CH; CH;- CH – C= CHarrow_forward(b) NABH, CH3 COCH,CH3 CH3CH2OH (c)arrow_forwardIdentify each organic compound as an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and provide a name for the compound. OH H;C-CH-CH2 H3Carrow_forward
- Propene (CH 3CH = CH 2) can be formed by dehydrating two different alcohols. Draw the structures of both alcohols.arrow_forwardThe condensed structural formula of an organic compound is CH3-CH2-CHBr-CHCl-CHCl-CHO. What is the name and type of this organic compound? 3-bromo-4,5-dichloro hexanal; aldehyde 4-bromo-2,3-dichloro hexanal; aldehyde 4-bromo-2,3-dichloro hexan-1-one; ketone 3-bromo-4,5-dichloro hexan-1-one; ketonearrow_forwardName each alkyne. CH,-C=C-CH, CH3 b. CH;-C=C-C-CH,-CH, CH3 c. CH=C-CH-CH2-CH2-CH, CH-CH, ČH,arrow_forward
- Identify each organic compound as an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and provide a name for the compound. CH3 CH; CH,-C-CH,-CH-CH,-CH,arrow_forwardName and draw a structural formula for the major product of each alkene addition reaction: CH S (a) CH₂C=CH₂ + HI →→→→ (b) CH 3 + HClarrow_forwardIndicate whether each statement is true or false. (a) Pentanehas a higher molar mass than hexane. (b) The longer the linearalkyl chain for straight-chain hydrocarbons, the higherthe boiling point. (c) The local geometry around the alkynegroup is linear. (d) Propane has two structural isomers.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
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