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Concept explainers
(a)
Interpretation: The given
Concept introduction:
Grignard reagents are
(b)
Interpretation: The given alkene is to be synthesized using Wittig reagent and organometallic reagent.
Concept introduction: Aldehyde can be directly converted to alkene using triphenyl phosphonium ylide. The geometry of the alkene formed, depends on the stability of the ylides.
Grignard reagents are organometallic compounds which are prepared using alkyl halides in presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.
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Chapter 21 Solutions
ORGANIC CHEMISTRY
- Problem 13.34 Synthesize each compound from cyclohexanol, ethanol, and any other needed reagents. a. b. C. d. e. OH XOH Br OHarrow_forward1. Draw the products of each nucleophilic substitution reaction a. b. D b OH C. d. e. f. Br 1 NaCN + NaOCH3 H₂Oarrow_forwardWhat is the major organic product obtained from the following reaction? A. B. CI لله مللی حمله C. D. فيarrow_forward
- Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.arrow_forwardDraw the products formed when each alkyl halide is treated with NaCN. а. b.arrow_forwardIdentify the following ethers or epoxides as symmetrical or asymmetrical. а. b. С. a.arrow_forward
- Draw a stepwise mechanism for the following reaction that forms ether D. D can be converted to the antidepressant uoxetine (trade name Prozac) in a single step.arrow_forwardDraw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form a substituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that can be used as a synthetic detergent to clean away dirtarrow_forwardAdd the reagent needed to accomplish the following transformation A do-> A. В. C. D.arrow_forward
- Draw the products formed when A or B is treated with each reagent. In some cases, no reaction occurs.a. NaBH4, CH3OHb. [1] LiAlH4; [2] H2Oc. [1] CH3MgBr (excess); [2] H2Od. [1] C6H5Li (excess); [2] H2Oe. Na2Cr2O7, H2SO4, H2Oarrow_forwardHow would you convert cyclohexanone into each compound using any required inorganic reagents and needed organic compounds? a. b.arrow_forward16.43 Draw the products of each reaction. a. b. d. HO C. H Lore L sob Br₂ FeBr3 e. NO₂ Br HNO3 H₂SO4 CI AICI 3 Cl₂ FeCl3 SO3 H₂SO4arrow_forward
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- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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