Concept explainers
(a)
Interpretation:
The products that are formed on the reaction of phosgene with excess of propan
Concept introduction:
Phosgene is an acid chloride of carbonic acid. The reaction of phosgene with an excess amount of an alcohol leads to the conversion of phosgene into an ester (dialkyl carbonate).
(b)
Interpretation:
The products that are formed on the reaction of phosgene with
Concept introduction:
Phosgene is an acid chloride of carbonic acid. The reaction of phosgene with an
(c)
Interpretation:
The synthesis of
Concept introduction:
Phosgene is an acid chloride of carbonic acid. The reaction of phosgene with an
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EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
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- which has the greatest acidity? a. 2-hexanol b. valeric acid c. naphtol d. ethyl propionate which produces effervescence when dissolved in 10% sodium bicarbonate? a. 2-hexanol b. valeric acid c. napththol d. ethyl propionatearrow_forward1. Which of the following organic compounds is the least polar? a. CH3CH2CHO b. CH3COCH3 c. CH3CH2CH2OH d. CH3CH2OCH3 e. CH3COOH 2. Which reagent can be used to convert acetic anhydride to acetic acid? a. NH3 b. CH3COO- c. CH3OH d. None of these e. H2Oarrow_forwardWhat is the major organic product obtained from the following reaction? A. B. Yo OH OH 1. LiAlH4 2. H3O+ C. D. H OHarrow_forward
- What is the major organic product obtained from the following reaction? A. 3-hydroxypropanoic acid B. 3-oxopropanoic acid C. propanedioic acid D. 1,3-propanediolarrow_forwardCH₂ CH₂ H KMnO4 H₂C 61. What type of reaction is catalyzed based on the chemical equation? A. Acid-catatalyzed dehydration B. Oxidation C. Reduction D. Williamson synthesis 62. What is the expected final product of this reaction? A. 3-methylbutanoic acid B. 2-methylbut-3-enoic acid C. 3-methyl-2-oxobutanoic acid D. 2-methylbutanoic acid 63. What is the functional group of the intermediate product in the reaction? A. Ketone B. Carboxylic acid C. Aldehyde D. Ether 个 5 ▸arrow_forwardChapter 1 (Carbonyl compounds I) Explain how the class I carbonyl compound reacts? What will be the product when ethylamine and propyl amine reacts with acetyl chloride? Why only one amide obtained after the reaction of acetyl chloride with a mixture of ethylamine and trimethylamine? Excess amine is required in the reaction of acetyl chloride with amine whereas excess alcohol is not required in the reaction of acetyl chloride and alcohol. Why? List the following ester in order of decreasing reactivities towards hydrolysis with reason: Methyl benzoate, p-nitro methyl benzoate and p-methoxy methyl benzoate The reaction of an ester with an amine is not as slow as the reaction of an ester with water or an alcohol. Explain with reason. Explain why the rate of aminolysis of an ester cannot be increased by H+, OH- or OR-. How can you activate the carboxylic acid? Is acid catalyzed hydrolysis of acetamide a reversible or an irreversible reaction. Explain. Chapter 2 (Carbonyl compounds II)…arrow_forward
- What is the major organic product obtained from the following reaction? A. B. OH OH 1.2 moles 2. H3O* C. MgBr هذه معه OHarrow_forwardConsider the structure of pent-2-ene, if it undergoes ozonolysis, which of the following final product is formed? a.Ethanal and Propanal b.Ethanal and Propanone c.CO2 and Propanal d.Ethanal and CO2arrow_forwardWhat are the best starting material and reagents needed to make N-methylpropanamide? a. propanol and H2CrO7 b. propanoic acid, methylamine c. propanoic acid, methylamine, and high heat d. propene, H2SO4, H2O, and high heat e. methanoic acid, propylamine, and high heatarrow_forward
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