(a)
Interpretation:
The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.
(b)
Interpretation:
The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.
(c)
Interpretation:
The reagent has to be proposed for the conversion of D to E for removing benzyl group.
Concept introduction:
Hydrogenolysis:
Metal catalyst gives the corresponding amine or alcohol.
(d)
Interpretation:
The reagent has to be proposed for the conversion of E to bidisomide.
(e)
Interpretation:
The possible stereoisomer’s has to be shown if the product is chiral.
Concept introduction:
Chiral:
A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.
Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.
Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.
Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.
Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.
Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.
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