Concept explainers
(a)
Interpretation:
The structural formula for 1-Bromo-2-chloro-4-ethylbenzene has to be drawn.
(b)
Interpretation:
The structural formula for m-Nitrocumene has to be drawn.
(c)
Interpretation:
The structural formula for 4-Chloro-1,2-dimethyl benzene has to be drawn.
(d)
Interpretation:
The structural formula for 3,5-Dinitrotoluene has to be drawn.
(e)
Interpretation:
The structural formula for 2,4,6-Trinitrotoluene has to be drawn.
(f)
Interpretation:
The structural formula for (2S,4R)-4-Phenyl-2-pentanol has to be drawn.
(g)
Interpretation:
The structural formula for p-Cresol has to be drawn.
(h)
Interpretation:
The structural formula for pentachlorophenol has to be drawn.
(i)
Interpretation:
The structural formula for 1-Phenylcyclopropanol has to be drawn.
(j)
Interpretation:
The structural formula for Triphenylmethane has to be drawn.
(k)
Interpretation:
The structural formula for Phenylethylene (styrene) has to be drawn.
(l)
Interpretation:
The structural formula for benzyl bromide has to be drawn.
Concept Introduction:
Structural formula gives information about how the atoms are arranged in a molecule.
(m)
Interpretation:
The structural formula for 1-Phenyl-1-butyne has to be drawn.
(n)
Interpretation:
The structural formula for (E)-3-Phenyl-2-propen-1-ol has to be drawn.
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Chapter 21 Solutions
EP ORGANIC CHEMISTRY-OWL V2 ACCESS
- Show how you might synthesize the following compounds starting with bromobenzene, andalkyl or alkenyl halides of four carbon atoms or fewer.(a) 3-phenylprop-1-ene (b) 5-methylhex-2-ene *(c) dec-5-enearrow_forward17) Which of the following compounds does not have the molecular formula C6H140? (a) 1-hexanol (b) 2-hexanol (c) 3-methyl-2-pentanol (d) 3-methyl-3-pentanol (e) Cyclohexanolarrow_forward13 Draw a structural formula for each compound. (a) 3-Chloropropene (b) 3-Methylcyclohexene (c) 1,2-Dimethylcyclohexene (d) trans-3,4-Dimethyl-3-heptene (e) Cyclopropene (f) 3-Hexynearrow_forward
- Write the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forwardDraw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexanearrow_forwardDraw structures corresponding to the following IUPAC names: (a) p-Bromochlorobenzene (c) m-Chloroaniline (b) p-Bromatolvene (d) 1-Chloro-3,5-dimethylbenzenearrow_forward
- Draw the structures for the following compounds.(a) 3-benzyl-4-bromohexane , 4,4-dimethylcyclohexene(b) trans-4,5-dibromohex-2-ene , cis-1,1-dibromo-2-ethyl-2,3-dimethylcyclobutanearrow_forwardWrite bond-line formulas for the following: (a) cis-3-Octene (b) trans-2-Hexene (c) 2,4-Dimethyl-2-pentene (d) trans-1-Chlorobut-2-ene (e) 4,5-Dibromo-l-pentenearrow_forwardDraw the structures of the following compounds:(i) 4-chloropentan-2-one (ii) But-2-en-l-alarrow_forward
- For each alkane, which mono brominated derivatives could you form in good yield by free-radical bromination?(a) cyclopentane (b) methylcyclopentane(c) 2-methylpentane (d) 2,2,3,3-tetramethylbutanearrow_forwardand (ii) KMnO4 in aqueous NaOH: 1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid (a) (b) 2. Draw structures corresponding to the following IUPAC names: (a) 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne (c) Hepta-1,5-diyne (d) 1-Methylcyclopenta-1,3-diene (1) 3. Draw and name all the possible pentyne isomers, C5H8. H H Ç-H [ Pent-1-yne] (2) 4. Predict the products of the following ring is inert to all the indicated reagents.) 4 H 4- (3) 4-C C = C-4 [3-methylbut -1-4 [Pent-2-yhdioselectivity where relevant. (The aromatic CH=CH2 Styrene (a) Styrene+H2 Pd, ? (c) Styrene+HBr ? (b) Styrene+Br2 → ? (d) Styrene+KMnO4 NaOH, H2O ? 5. Suggest structures for alkenes that give the following reaction products. There may be more than one answer for some cases. HyPd catalyst (a) ? Br₂ in CH2Cl2 (b) ? HBr (c) ? 2-Methylhexane 2,3-Dibromo-5-methylhexane 2-Bromo-3-methylheptane CH3 HO OH CH3CHCH2CHCHCH2CH3 KMnO4OH (d) ? H₂Oarrow_forwardWrite the bond line formula of the following compounds: (a) 4-methyl-2-hexene, two geometrical (stereoisomers) isomers (b) 3-fluoro-2-methylheptanol (3-fluoro-2-methylheptan-1-ol) (c) 4-methyl-hex-1-yn-3-olarrow_forward
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