a) N -Methyl propanamide and N, N - dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

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Answer 1

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Draw a structural formula for each amine and amine derivative. (a) N,N-Dimethylaniline (b) Triethylamine (c) tert-Butylamine (d) 1,4-Benzenediamine (e) 4-Aminobutanoic acid (f) (R)-2-Butanamine (g) Benzylamine (h) trans-2-Aminocyclohexanol (i) 1-Phenyl-2-propanamine (amphetamine) (j) Lithium diisopropylamide (LDA) (k) Benzyltrimethylammonium hydroxide (Triton B)

1. Draw structures for the following: (a) N,N-dimethylpentanamide (b) Acetamide(c) 2,3-dimethylpentanamide (d) N-ethylbenzamide

Draw a structural formula for each amine. (a) 2-Butanamine (b) 1-Octanamine (c) 2,2-Dimethyl-1-propanamine (d) 1,5-Pentanediamine (e) 2-Bromoaniline (f) Tributylamine

Answer 2

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Answer 3

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Answer 4

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Answer 5

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 6

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 7

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 8

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 9

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 10

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 11

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 12

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 13

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 14

Expert Solution & Answer

Answer 15

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Answer 16

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Answer 17

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

a) N -Methyl propanamide and N, N - dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

a) N-Methyl propanamide and N, N- dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride. Interpretation: To distinguish spectroscopically between the following isomer pairs.

d) Ethyl propanate and propyl acetate. Interpretation: To distinguish spectroscopically between the following isomer pairs.

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Chapter 21 Solutions

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.