To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate. Chloral hydrate, the product of the reaction, is a sedative that can be lethal. A cocktail laced with it is known—in detective novels,at least—as a “Mickey Finn.” Explain why an aqueous solution of trichloroacetaldehyde is almost all hydrate.

When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate. Chloral hydrate, the product of the reaction, is a sedative that can be lethal. A cocktail laced with it is known—in detective novels, at least—as a “Mickey Finn.” Explain why an aqueous solution of trichloroacetaldehyde is almost all hydrate.

Write the mechanism for the following reactions: 1. the acid-catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine 2. the acid-catalyzed hydrolysis of an enamine to a carbonyl compound and a secondary amine a. How do the two mechanisms differ?

Answer 2

Question

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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Answer 3

Question

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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Answer 4

Question

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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Answer 5

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Answer 6

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Answer 7

Chapter 21.SE, Problem 81AP

Interpretation Introduction

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Answer 8

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Answer 11

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Solution Summary: The author explains that to explain the reactivity of an amide is formed from an acid chloride or anhydride, two moles of base are required.

Concept explainers

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

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Chapter 21 Solutions

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Solution Summary: The author explains that to explain the reactivity of an amide is formed from an acid chloride or anhydride, two moles of base are required.

Concept explainers

Interpretation: To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

To explain the reactivity of an amide is formed from an acid chloride or an anhydride, two moles of base are required. However, when an ester is used as the starting material, only one equivalent of base is needed.