Concept explainers
(a)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 1
Figure 2
The first step of the reaction involves the bromination of cyclohexanone in the presence of acetic acid. It results in the formation of
The formation of the given product from cyclohexanone and organic halides having
(b)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 3
Figure 4
The full form of LDA is lithium diisopropylamide. It is a strong base. In the first step, cyclohexanone reacts with LDA to form an intermediate, which is followed by a reaction with allyl bromide to produce
The formation of the given product from cyclohexanone and organic halides having
(c)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 5
Figure 6
The full form of LDA is lithium diisopropylamide. It is a strong base. In the first step, cyclohexanone reacts with LDA to form an intermediate, which is followed by a reaction with methyl bromide to produce
The formation of the given product from cyclohexanone and organic halides having
(d)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 7
Figure 8
Figure 9
The first step of the reaction involves the bromination of cyclohexanone in the presence of
The formation of the given product from cyclohexanone and organic halides having
(e)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 10
Figure 11
Figure 12
The full form of LDA is lithium diisopropylamide. It is a strong base. In the first step, cyclohexanone reacts with LDA to form an intermediate, which is followed by a reaction with ethyl bromide to produce
The formation of the given product from cyclohexanone and organic halides having
(f)
Interpretation:
The synthesis of a given compound from cyclohexanone and organic halides having
Concept introduction:
The synthesis of the products relies upon the type of reactants and reagents that are used during the reactions. The energy of a target molecule should be low because it increases the stability of a molecule that results in the formation of a molecule with high yield. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
Answer to Problem 23.66P
The synthesis of a given compound from cyclohexanone and organic halides having
Explanation of Solution
The formation of the given product from cyclohexanone and organic halides having
Figure 13
Figure 14
The first step involves the bromination of cyclohexanone to give bromo product, which on reaction with
The formation of the given product from cyclohexanone and organic halides having
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Chapter 23 Solutions
Organic Chemistry
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- Devise a stepwise synthesis of each compound from dicyclopentadiene using a Diels–Alder reaction as one step. You may also use organic compounds having ≤ 4 C's, and any required organic or inorganic reagents.arrow_forwardDevise a synthesis of each compound from benzene and organicalcohols containing four or fewer carbons. You may also use anyrequired organic or inorganic reagents.arrow_forwardA key step in the synthesis of the antidepressant paroxetine (trade name Paxil) involves a Williamson ether synthesis of the acyclic ether in X. Draw two different routes to this ether and state which is preferred.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning