(a)
Interpretation:
The structure of complex pentamminenitrito-N-cobalt(III)ion needs to be drawn.
Concept introduction:
The structure of chelate complex is formed in such a way that the ligands are linked through covalent bonds wherein the metal ion is at the centre with ligands on either side of the metal ion.
The structures gets arranged to give a square planar, octahedral or tetrahedral sturcutre. Structures gets arranged to form a stable or symmetrical geometry.
(b)
Interpretation:
The structure of chelate complex ethylenediaminedithiocyanato-S-copper(II) needs to be drawn.
Concept introduction:
Structure of chelates are formed in such a way that multidentate ligands uses more that one atom to bind to a metal ion wherein the ligands are attached to the central atom. It is mostly in the form of rings or have square planar and tetrahedral structures. The geometry needs to be stable and hence, the molecules undergo rearrangement.
(c)
Interpretation:
The structure of hexaaquanickel(II) ion needs to be drawn.
Concept introduction:
Chelate indicates those structure which are cyclic in nature and metal ions unite with organic or inorganic molecules. The presence of mulitdentate ligands uses more atoms to bind to metal ion where ligands get attached to the central atom. The structure is mostly in the form of rings. The structure is
either square planar or tetrahedral. The geometry needs to be stable for which the molecules undergo rearrangement.
Want to see the full answer?
Check out a sample textbook solutionChapter 24 Solutions
Mastering Chemistry With Pearson Etext -- Standalone Access Card -- For General Chemistry: Principles And Modern Applications (11th Edition)
- Which of the following statement(s) is( are) true? a. The coordination number of a metal ion in an octahedral complex ion is 8. b. All tetrahedral complex ions are low-spin. c. The formula for triaquatrianuninechromiwn(III) sulfate is [Cr(H2O)3(NH3)](SO4)3. d. The electron configuration of Hf2+ is [Xe]4f126s2. e. Hemoglobin contains Fe3+.arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forwardDefine the terms complex ion, ligand, and coordination number. Use an example to illustrate the use of these terms.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning