Chapter 24, Problem 3E

Interpretation Introduction

(a)

Interpretation:

The name of the coordinate compound $\left[\text{Ag}{\left({\text{NH}}_{\text{3}}\right)}_{\text{2}}\right]\text{Cl}$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.

Interpretation Introduction

(b)

Interpretation:

The name of the coordinate compound $\left[\text{Cu}{\left({\text{H}}_{\text{2}}\text{O}\right)}_{\text{2}}{\left({\text{NH}}_{\text{3}}\right)}_4\right]{\text{SO}}_4$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.

Interpretation Introduction

(c)

Interpretation:

The name of the coordinate compound ${\text{PtCl}}_{\text{2}}\left(\text{en}\right)$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.

Interpretation Introduction

(d)

Interpretation:

The name of the coordinate compound ${\left[\text{CrBr}{\left({\text{H}}_{\text{2}}\text{O}\right)}_5\right]}^{2+}$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.

Interpretation Introduction

(e)

Interpretation:

The name of the coordinate compound

$\text{Rb}\left[{\text{AgF}}_{\text{4}}\right]$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.

Interpretation Introduction

(f)

Interpretation:

The name of the coordinate compound ${\text{Na}}_{\text{2}}\left[\text{Fe}{\left(\text{CN}\right)}_2\text{NO}\right]$ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The name of the coordinate compound depends on the type of the coordination compound. The name of the positive ion is always written first. Within the coordination sphere (written in the square brackets) name of the negative ions is written by addition of suffix “o”. The name of the neutral ligands is written without any special end. Positive ligands are written followed by suffix “ium”. For more than 1 type of ions, the name is written in alphabetical order. After the name of all the ligand, the name of metal ion is written. The name of the metal ion is followed by its oxidation state in Roman number.