Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material. Concept Introduction: The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of P d catalyst. Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Question

Give the series of reactions below, identify and give the iupac name for the following compounds, in short identify and name A,B,C

Answer 1

Question

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

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Give the series of reactions below, identify and give the iupac name for the following compounds, in short identify and name A,B,C

Below are two potential methods for preparing the same ether (Option A and B), but only one of them is actually successful. Identify the successful approach (A or B)

2. Provide reagents/conditions to accomplish the following syntheses. Several steps are required in some cases.

Answer 2

Question

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

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Answer 3

Question

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

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Answer 4

Question

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

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Answer 5

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Answer 6

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Answer 7

Chapter 24.3, Problem 24.1P

(a)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by Heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

Concept Introduction:

The H atom on an alkene such as vinylic hydrogen is substituted by a haloalkene or haloarene is often in the presence of base and small amount of Pd catalyst.

Reaction is highly regioselective in which formation of a new carbon-carbon bond occurs at a less substituted carbon of a double bond.

Answer 10

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Answer 21

Ch. 24.3 - Prob. 24.1P Ch. 24.3 - Prob. 24.2P Ch. 24.4 - Prob. 24.3P Ch. 24.5 - Show how the following compound can be prepared...Ch. 24.5 - Prob. 24.5P Ch. 24.5 - Prob. 24.6P Ch. 24.6 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that given compound has to be prepared by heck reaction using methyl-2-propenaote as the starting material.

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Chapter 24 Solutions