The hybridization and geometry of C - O - P bond angle in figure 25.2 using resonance structures. Concept Introduction: Valence bond electron repulsion theory describes the shape and the geometry of a molecule. It also helps us to determine the bond angles between the atoms in a molecule. From the predicted bond angles the hybridization of a molecule can also be predicted.

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 25, Problem 25.6P

Interpretation Introduction

Interpretation:

The hybridization and geometry of C-O-P bond angle in figure 25.2 using resonance structures.

Concept Introduction:

Valence bond electron repulsion theory describes the shape and the geometry of a molecule. It also helps us to determine the bond angles between the atoms in a molecule. From the predicted bond angles the hybridization of a molecule can also be predicted.

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Describe the molecular geometry and hybridization of the N, P, or S atoms in each of the following compounds. (a) H3PO4, phosphoric acid, used in cola soft drinks (b) NH4NO3, ammonium nitrate, a fertilizer and explosive (c) S2Cl2, disulfur dichloride, used in vulcanizing rubber (d) K4[O3POPO3], potassium pyrophosphate, an ingredient in some toothpastes

Describe the molecular geometry and hybridization of the N, P, or S atoms in each of the following compounds.(a) H3PO4, phosphoric acid, used in cola soft drinks(b) NH4NO3, ammonium nitrate, a fertilizer and explosive(c) S2Cl2, disulfur dichloride, used in vulcanizing rubber(d) K4[O3POPO3], potassium pyrophosphate, an ingredient in some toothpastes

The sulfate ion can be represented with four S-O bonds or with two S-O and two So=O bonds.(a) Which representation is better from the standpoint of formal charges?(b) What is the shape of the sulfate ion, and what hybrid orbitals of S are postulated for the σ bonding?(c) In view of the answer to part (b), what orbitals of S must be used for the π bonds? What orbitals of O?(d) Draw a diagram to show how one atomic orbital from S and one from O overlap to form a π bond.

Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 25, Problem 25.6P

Interpretation Introduction

Interpretation:

The hybridization and geometry of C-O-P bond angle in figure 25.2 using resonance structures.

Concept Introduction:

Valence bond electron repulsion theory describes the shape and the geometry of a molecule. It also helps us to determine the bond angles between the atoms in a molecule. From the predicted bond angles the hybridization of a molecule can also be predicted.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 25, Problem 25.6P

Interpretation Introduction

Interpretation:

The hybridization and geometry of C-O-P bond angle in figure 25.2 using resonance structures.

Concept Introduction:

Valence bond electron repulsion theory describes the shape and the geometry of a molecule. It also helps us to determine the bond angles between the atoms in a molecule. From the predicted bond angles the hybridization of a molecule can also be predicted.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 25, Problem 25.6P

Interpretation Introduction