There are eight possible stereoisomers of the aldopentoses. Concept introduction: There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Question

(d) Draw the structure of the expected product when monosaccharide B undergo mutarotation upon dissolving in water in the presence of Tollens reagent (AGNO3, NHẠOH). он OH O. OH OH OH monosaccharide B

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

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(d) Draw the structure of the expected product when monosaccharide B undergo mutarotation upon dissolving in water in the presence of Tollens reagent (AGNO3, NHẠOH). он OH O. OH OH OH monosaccharide B

Complete the following for each of the following structures below. Determine whether it is an aldohexose, aldopentose, ketohexose or ketopentose. Label the chiral carbon atoms using an asterisk. Determine the number of stereoisomers it can have. Label the molecule as a D or an L sugar.

1. Which of the following is not true to the monosaccharide below? H. ОН но- -H- но ОН ĆH2OH O It is the Fischer Projection of D-glucose. It is an aldohexose having 4 chiral centers and 24 stereoisomers. It is has a D-glucose because OH- group bonded to the highest numbered chiral C is pointing to the right. It is a polyhydroxy ketone having 8 enantiomeric pair.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Expert Solution & Answer

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Answer 5

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Answer 6

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Answer 7

Chapter 25.4, Problem 10P

Interpretation Introduction

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Answer 8

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Ch. 25.1 - Prob. 1P Ch. 25.2 - Prob. 2P Ch. 25.2 - Prob. 3P Ch. 25.2 - Prob. 4P Ch. 25.2 - Prob. 5P Ch. 25.3 - Prob. 6P Ch. 25.3 - Prob. 7P Ch. 25.4 - Prob. 8P Ch. 25.4 - Prob. 9P Ch. 25.4 - Prob. 10P

There are eight possible stereoisomers of the aldopentoses. Concept introduction: There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Solution Summary: The author explains the Fischer projection formula of the given sugar has the C-4 hydroxyl group on the right.

Concept explainers

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Chapter 25 Solutions

There are eight possible stereoisomers of the aldopentoses. Concept introduction: There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Solution Summary: The author explains the Fischer projection formula of the given sugar has the C-4 hydroxyl group on the right.

Concept explainers

Interpretation: There are eight possible stereoisomers of the aldopentoses. Concept introduction: There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.

Chapter 25 Solutions

Interpretation:

There are eight possible stereoisomers of the aldopentoses.

Concept introduction:

There are three chiral carbons in aldopentoses and from which eight possible stereoisomers are obtained.