ORGANIC CHEMISTRY-EBOOK>I<
9th Edition
ISBN: 9781305084414
Author: McMurry
Publisher: INTER CENG
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Chapter 25.SE, Problem 50AP
Interpretation Introduction
Interpretation:
There are only 4 D-2 ketohexoses.
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Identify the type of glycosidic bond in the following disaccharide.
CH,OH
H
H
ОН Н
CH2
H
H
H
ОН Н
HO
ОН
H.
ОН
HO
H
H
OH
O B-1,4-glycosidic bond
O a-1,4-glycosidic bond
O B-1,6-glycosidic bond
O a-1,6-glycosidic bond
Which disaccharide contains an a(1-4) glycosidic bond?
CH2OH
CH,OH
CH2OH
CH2OH
OH
OH
OH
OH
OH
OH
ÓH
ÓH
Click the "draw structure" button to launch the drawing utility.
Convert the cyclic form to an acyclic monosaccharide.
CH₂OH O-
H
H
OH
HO
H
H
OH
draw structure
1b)Use a simple model to convert the
following Fischer projection to a line structure
showing stereochemistry
Br
OHC CH3
HO–|CH,CH3
H
S
d
ww
b
H
Chapter 25 Solutions
ORGANIC CHEMISTRY-EBOOK>I<
Ch. 25.1 - Prob. 1PCh. 25.2 - Prob. 2PCh. 25.2 - Prob. 3PCh. 25.2 - Prob. 4PCh. 25.2 - Prob. 5PCh. 25.3 - Prob. 6PCh. 25.3 - Prob. 7PCh. 25.4 - Prob. 8PCh. 25.4 - Prob. 9PCh. 25.4 - Prob. 10P
Ch. 25.5 - Prob. 11PCh. 25.5 - Prob. 12PCh. 25.5 - Prob. 13PCh. 25.5 - Prob. 14PCh. 25.5 - Prob. 15PCh. 25.6 - Prob. 16PCh. 25.6 - Prob. 17PCh. 25.6 - Prob. 18PCh. 25.6 - Prob. 19PCh. 25.6 - Prob. 20PCh. 25.6 - Prob. 21PCh. 25.6 - Prob. 22PCh. 25.6 - Prob. 23PCh. 25.7 - Prob. 24PCh. 25.8 - Show the product you would obtain from the...Ch. 25.SE - Prob. 26VCCh. 25.SE - Prob. 27VCCh. 25.SE - Prob. 28VCCh. 25.SE - Prob. 29VCCh. 25.SE - Prob. 30MPCh. 25.SE - Prob. 31MPCh. 25.SE - Glucosamine, one of the eight essential...Ch. 25.SE - D-Glicose reacts with acetone in the presence of...Ch. 25.SE - Prob. 34MPCh. 25.SE - Prob. 35MPCh. 25.SE - Prob. 36APCh. 25.SE - Prob. 37APCh. 25.SE - Prob. 38APCh. 25.SE - Prob. 39APCh. 25.SE - Prob. 40APCh. 25.SE - Assign R or S configuration to each chirality...Ch. 25.SE - Prob. 42APCh. 25.SE - Prob. 43APCh. 25.SE - Prob. 44APCh. 25.SE - Prob. 45APCh. 25.SE - Prob. 46APCh. 25.SE - Prob. 47APCh. 25.SE - Prob. 48APCh. 25.SE - Prob. 49APCh. 25.SE - Prob. 50APCh. 25.SE - Prob. 51APCh. 25.SE - Prob. 52APCh. 25.SE - Prob. 53APCh. 25.SE - Prob. 54APCh. 25.SE - Prob. 55APCh. 25.SE - Prob. 56APCh. 25.SE - Prob. 57APCh. 25.SE - Prob. 58APCh. 25.SE - Prob. 59APCh. 25.SE - Prob. 60APCh. 25.SE - Prob. 61APCh. 25.SE - Prob. 62APCh. 25.SE - Prob. 63APCh. 25.SE - D-Mannose reacts with acetone to give a...Ch. 25.SE - Prob. 65APCh. 25.SE - Prob. 66APCh. 25.SE - Prob. 67APCh. 25.SE - Prob. 68APCh. 25.SE - Prob. 69APCh. 25.SE - Prob. 70APCh. 25.SE - Prob. 71AP
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- D The following disaccharide contains a(n) (blank]-glycosidic linkage. HO CH₂OH ОН Oa-1,4 OB-1,4 a-1,6 O B-1,6 0 OH Question 6 double bond ssignments/syllabus ester bond ether bond amide bond HO A glycosidic bond between two monosaccharides can also be classified as a(n) [blank). OH OH Melebi OH MacBook Proarrow_forwardProvide the IUPAC name for the following tetrasaccharide. но- HO но но- но- но, но- HO но но. OHarrow_forwardConsider two disaccharides OH CH₂OH OH maltose OH CH OH OH - OH OH OH CH₂OH OH fructose OH OH CH OH Which of the two disaccharides contains a hemiacetal? Which of the two disaccharides contains the acetal? CHLOH OHarrow_forward
- O deoxy carboxylic acid pentose O carboxylic acid pentose O aldopentose Question 6 Classify the following monosaccharide. C-H H NH2 Но H -OH- ČH,OH O aminohexose O ketotetrose O deoxyhexose O aldohexose O carboxylic acid heptose Question 7 Classify the following monosaccharide. CH.OH MacBook Proarrow_forwardWhich characteristic is shared by the ring forms of the given monosaccharides? * CH2OH CHO O= H- HO- HO- но- H- но- Но H H- -OH ČH,OH ČH2OH Both exist mainly as furanoses. Both contain a hemiacetal bond. Both can undergo mutarotation. O Both exist mainly as pyranoses.arrow_forwardOH НО HO OH НО Но OH ОН ОН OH What are the monosachharides that make up this trisaccharide? O a-D-glucopyranose, a-D-galactopyranose, a-D-fructofuranose a-D-glucopyranose, a-D-galactopyranose, B-D-fructofuranose a-D-glucopyranose, a-D-glucopyranose, B-D-fructofuranose a-D-galactopyranose, a-D-glucopyranose, a -D-fructofuranosearrow_forward
- How to draw C3H4 in Ketone form?arrow_forwardWhich of the following is the correct pair of monosaccharides needed 2 to form the given glycoside? * CH2OH CH-OH CH2OH OH он он OH OH a-D-fructofuranose & B-D-glucopyranose a-D-sorbofuranose & B-D-allopyranose a-D-mannofuranose & B-D-glucopyranose O a-D-sorbofuranose & B-D-galactopyranosearrow_forward2. Sucrose is a disaccharide formed from the condensation of glucose and fructose sugars. Draw the structure of sucrose that results from the condensation reaction between the indicated -OH groups. CH2OH 1, CH,OH он 1. OH но CH,OH OH HO H он OHarrow_forward
- in the following molecule the glycosidic bond is circled. CH2OH CH2OH H CH2OH OH HO H H НО H. ОН ÓH True Falsearrow_forwardFollowing is the Haworth structure of a disaccharide. Identify the type of glycosidic bond in this disaccharide. CH₂OH H HO H OH H H OH H H a-1,6-glycosidic bond O a,B-1,2-glycosidic bond O B-1,4-glycosidic bond O a-1,4-glycosidic bond CH₂OH H OH H H OH H OH B a hparrow_forward12.) Three of the five disaccharides above contain a 1, 4 glycosidic linkages. Which TWO molecules do NOT contain a 1, 4 glycosidic linkages? Encircle the letter of your two choices. CH,OH CH,OH CHOH CH,OH A OH OH ÓH он CH,OH CH,OH CH,OH OH D OH HOH,C CH,OH CH,OH CH,OHO. E OH CH,OH ÓH H. OH OHarrow_forward
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