Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 25.6, Problem 6P
Write the structural formula and give the IUPAC name for the fatty acid from which
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13. Circle the fatty acid in each pair that has the higher melting temperature.
(a) 18:1Δ9 18:2 Δ 9,12
(b) 18:0 18:1 Δ 9
(c) 18:0 16:0
14. Describe the dependence of the melting point of a fatty acid upon (a) chain length and (b)
unsaturation; (c) explain these dependencies in molecular terms.
Chapter 25 Solutions
Organic Chemistry - Standalone book
Ch. 25.2 - What fatty acids are produced on hydrolysis of...Ch. 25.3 - Give the structure of the keto acyl-ACP formed...Ch. 25.4 - Prob. 3PCh. 25.4 - Prob. 4PCh. 25.5 - Prob. 5PCh. 25.6 - Write the structural formula and give the IUPAC...Ch. 25.6 - Prob. 7PCh. 25.7 - Locate the isoprene units in each of the...Ch. 25.7 - Prob. 9PCh. 25.9 - Prob. 10P
Ch. 25.9 - Prob. 11PCh. 25.10 - Prob. 12PCh. 25.11 - Prob. 13PCh. 25.11 - Prob. 14PCh. 25.12 - Prob. 15PCh. 25.16 - Prob. 16PCh. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Pyrethrins are a group of naturally occurring...Ch. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - Prob. 28PCh. 25 - A synthesis of triacylglycerols has been described...Ch. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33DSPCh. 25 - Prob. 34DSPCh. 25 - Prob. 35DSPCh. 25 - Prob. 36DSPCh. 25 - Prob. 37DSPCh. 25 - Prob. 38DSP
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- What is the melting point order of the following fatty acids (lowest to highest), the ratio in parenthesis is single bonds to double bonds. Lauric (12:0), Palmitic (16:0), Palmitoleic (16:1), and Oleic (18:1).arrow_forwardClassify the following fatty acids. CHOICES: LCFA MCFA SCFA Lauric acid Oleic acid Butyric acid Stearic acidarrow_forwardWhat portion of fatty acid molecules would be found on the outside of a miscelle? A. long hydrophilic tail portion B. long hydrophobic tail portion C. carboxylate hydrophilic head portion D. carboxylate hydrophobic head portionarrow_forward
- Explain the effect of different additives on the stability of linoleic acid emulsion against oxidation.arrow_forwardFrom Table 1.1 indicates, among other things, the melting points of various fatty acids. Analyze the trend that the melting points of saturated fatty acids follow, from n-dodecanoic (CH3-(CH2) 10-COOH) to n-tetracosanoic (CH3-(CH2)22-COOH), and answer both next questions. Briefly justify your answers. i) What value would you expect the melting point of triacontanoic acid (CH3-(CH2) 28-COOH) to have? Choose one of the following options:a) More than 200 ° Cb) About 94 ° Cc) Less than 86 ° Cd) Exactly 86.1 ° C ii) What value would you expect the melting point of octanoic acid (CH3-(CH2) 6-COOH) to have? Choose one of the following options:a) 43.5 ° Cb) -20 ° Cc) About 20 ° Carrow_forwardRank the fatty acids in order of increasing melting pointarrow_forward
- Show the formation of the phosphoglyceride containing glycerol, palmitic acid, palmitoleic acid, phosphoric acid and ethanolamine.arrow_forwardDuring beta-oxidation of the fatty acid shown in the diagram below the bond at position will be cleaved to produce Acetyl-CoA and a fatty acid shortened by two carbon atoms.arrow_forwarda) Provide as specific a name as you can for the molecule b) Name the fatty acid that is part of this molecule c) How does the structure of this molecule contribute to its function? all three plz thxarrow_forward
- In a dietary context, classify each of the following fatty acids as an essential fatty acid or as a nonessential fatty acid. a. Lauric acid (12:0) b. Linoleic acid (18:2) c. Myristic acid (14:0) d. Palmitoleic acid (16:1)arrow_forwardIn each of the following pairs of fatty acids, select the fatty acid that has the higher melting point. a. 14:0 acid and 18:0 acid b. 20:4 acid and 20:5 acid c. 18:3 acid and 20:3 acid d. 16:0 acid and 16:1 acidarrow_forward
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