ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
10th Edition
ISBN: 9781260001099
Author: Carey
Publisher: MCG
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Chapter 26, Problem 29P
Interpretation Introduction

Interpretation:

The amino acid obtained by the hydrolysis of the given compound in concentrated hydrochloric acid for several hours at 100°C is to be determined. Whether that amino acid is optically active or not, is to be discussed.

Concept Introduction:

α-amino acids contain an amine group attached to the alpha position on the carbon chain that contains the carboxylic acid group.

An optically active amino acid has a carbon atom in its structure, which is attached to the four different atoms or groups.

There is no symmetry element in an optically active amino acid.

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The amino acid (S)-alanine has the physical characteristics listed under the structure. How does the melting point of a racemic mixture of (R)- and (S)-alanine compare to the melting point of (S)-alanine?
The amino acid (S)-alanine has the physical characteristics listed under the structure. a.What is the melting point of (R)-alanine? b.How does the melting point of a racemic mixture of (R)- and (S)-alanine compare to the melting point of (S)-alanine? c. What is the specific rotation of (R)-alanine, recorded under the same conditions as the reported rotation of (S)-alanine? d.What is the optical rotation of a racemic mixture of (R)- and (S)-alanine? e.Label each of the following as optically active or inactive: a solution of pure (S)alanine; an equal mixture of (R)- and (S)-alanine; a solution that contains 75% (S)- and 25% (R)-alanine.
(1) Which is an achiral amino acid? (2) Which is the basic and the acidic amino acid? (3) Which is a a cyclic amino acid?
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Biomolecules - Protein - Amino acids; Author: Tutorials Point (India) Ltd.;https://www.youtube.com/watch?v=ySNVPDHJ0ek;License: Standard YouTube License, CC-BY