Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 27.1, Problem 1P
Carnauba wax, used in floor and furniture polishes, contains an ester of a C32 straight-chain alcohol with a C20 straight-chain
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Chapter 27 Solutions
Organic Chemistry
Ch. 27.1 - Carnauba wax, used in floor and furniture...Ch. 27.1 - Draw structures of glyceryl tripalmitate and...Ch. 27.2 - Prob. 3PCh. 27.2 - Write the saponication reaction of glyceryl...Ch. 27.4 - Prob. 5PCh. 27.5 - Prob. 6PCh. 27.5 - Prob. 7PCh. 27.6 - Draw the following molecules in chair...Ch. 27.6 - Lithocholic acid is an A–B cis steroid found in...Ch. 27.7 - Prob. 10P
Ch. 27.SE - Prob. 11VCCh. 27.SE - Propose a biosynthetic pathway for the...Ch. 27.SE - Identify the following fatty acid, and tell...Ch. 27.SE - Prob. 14MPCh. 27.SE - Prob. 15MPCh. 27.SE - Prob. 16MPCh. 27.SE - Prob. 17APCh. 27.SE - Fats can be either optically active or optically...Ch. 27.SE - Prob. 19APCh. 27.SE - Show the products you would expect to obtain from...Ch. 27.SE - Draw a Newman projection along the C2-C3 bond of...Ch. 27.SE - The plasmalogens are a group of lipids found in...Ch. 27.SE - Prob. 23APCh. 27.SE - Prob. 24APCh. 27.SE - Prob. 25APCh. 27.SE - Prob. 26APCh. 27.SE - Prob. 27APCh. 27.SE - Prob. 28APCh. 27.SE - Prob. 29APCh. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Assume that acetyl CoA containing a 14C isotopic...Ch. 27.SE - Prob. 34APCh. 27.SE - Draw the most stable chair conformation of...Ch. 27.SE - Draw the most stable chair conformation of...Ch. 27.SE - Prob. 37APCh. 27.SE - Prob. 38APCh. 27.SE - Prob. 39APCh. 27.SE - What product would you obtain by reduction of...Ch. 27.SE - Prob. 41APCh. 27.SE - Eleostearic acid, C18H30O2, is a rare fatty acid...Ch. 27.SE - Prob. 43APCh. 27.SE - Prob. 44APCh. 27.SE - Propose a synthesis of diethylstilbestrol (Problem...Ch. 27.SE - Prob. 46APCh. 27.SE - Cembrene, C20H32, is a diterpenoid hydrocarbon...Ch. 27.SE - α-Fenchone is a pleasant-smelling terpenoid...Ch. 27.SE - Prob. 49APCh. 27.SE - Propose a mechanism for the biosynthesis of the...
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- Eleostearic acid, C18H30O2, is a rare fatty acid found in the tung oil used for finishing furniture. On ozonolysis followed by treatment with zinc, eleostearic acid furnishes one part pentanal, two parts glyoxal (OHC-CHO), and one part 9-oxononanoic acid [OHC(CH2)7CO2H]. What is the structure of eleostearic acid?arrow_forwardDraw the products formed when benzoic acid (C6H5CO2H) is treated with CH3OH having its O atom labeled with 18O (CH318OH). Indicate where the labeled oxygen atom resides in the products.arrow_forwardDraw the major product of the reaction between 1-butanol and Na2Cr2O7, H2SO4, H2O.arrow_forward
- Draw the products a. Pentyl butanoate reacts with water and NaOH b. Acetic anhydride reacts with ethanol c. 3-hexanone reacts with two equivalents of isopropyl alcohol d. Hexanal reacts with NaBH4 and CH3OHarrow_forwardIf a carboxylic acid is dissolved in isotopically labeled methanol (CH3 18OH) and an acid catalyst is added, where will the label reside in the product?arrow_forwardHow would the reactant react with (CH2=CH)2CuLi ?arrow_forward
- Compound A boils at 25 C Compound B boils at 80 C Which has the strong IMFs? OB O Aarrow_forwardDraw the products formed when (CH3)2C=CH2 is treated with following reagent. [1] BH3; [2] H2O2, HO−arrow_forwardWhich of the following statements is INCORRECT? The carbon atom in formic acid is sp2 hybridized. Carboxylic acids with 5 or fewer carbons are soluble in water. Carboxylic acids are weaker acids than HCl. Carboxylic acids dissociate completely in water.arrow_forward
- 7. The following compounds are isomeric esters derived from acetic acid, each with formula C5H10O2. Draw the structures of the two esters?arrow_forwardDraw a structural formula of the principal product formed when ethyl benzoate is treated with reagent. Q.) C6H5MgBr (two equivalents), then HCl/H2Oarrow_forwardIn a 0.28 mM aqueous solution of trimethylacetic acid (C4H9CO2H), what is the percentage of trimethylacetic acid that is dissociated?arrow_forward
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