Organic Chemistry (Looseleaf)
4th Edition
ISBN: 9780077640194
Author: SMITH
Publisher: MCG
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Chapter 28, Problem 28.20P
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Interpretation: The structure of
Concept introduction: The
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What product or products are obtained when d-galactose reacts with each of the following?
a. nitric acid + ∆ b. Ag+, NH3, HO- c. NaBH4, followed by H3O+ d. excess CH3I + Ag2O e. Br2 in water f. ethanol + HClg. 1. hydroxylamine/trace acid
2. acetic anhydride/∆
3. HO-/H2O
Predict the products obtained when d-galactose reacts with each reagent. (c) CH3OH, H + (d) Ag(NH3) 2+ -OH(e) H2, Ni
What are the products when D-ribose is treated under the following conditions?
1) NH2OH, CH3OH, CH3ONa
2) Ac2O, 100 C
3) CH3OH, CH3ONa
4) H2O, H3O+
What are the products when D-ribose is treated under the following conditions?
1) Br2 / H2O
2) Ca(OH)2
3) Fe2(SO4)3
4) H2O2.
Chapter 28 Solutions
Organic Chemistry (Looseleaf)
Ch. 28 - Prob. 28.1PCh. 28 - Prob. 28.2PCh. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5PCh. 28 - Prob. 28.6PCh. 28 - Prob. 28.7PCh. 28 - Prob. 28.8PCh. 28 - Prob. 28.9PCh. 28 - Prob. 28.10P
Ch. 28 - Prob. 28.11PCh. 28 - Prob. 28.12PCh. 28 - Prob. 28.13PCh. 28 - Prob. 28.14PCh. 28 - Prob. 28.15PCh. 28 - Prob. 28.16PCh. 28 - Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.18PCh. 28 - Prob. 28.19PCh. 28 - Prob. 28.20PCh. 28 - Prob. 28.21PCh. 28 - Draw the products formed when D-arabinose is...Ch. 28 - Prob. 28.23PCh. 28 - Prob. 28.24PCh. 28 - Prob. 28.25PCh. 28 - Prob. 28.26PCh. 28 - Prob. 28.27PCh. 28 - Prob. 28.28PCh. 28 - Prob. 28.29PCh. 28 - Prob. 28.30PCh. 28 - Prob. 28.31PCh. 28 - Prob. 28.32PCh. 28 - Prob. 28.33PCh. 28 - Prob. 28.34PCh. 28 - Problem-28.35
Draw the structures of the...Ch. 28 - Prob. 28.36PCh. 28 - 28.37 Convert each ball-and-stick model to a...Ch. 28 - Prob. 28.38PCh. 28 - Prob. 28.39PCh. 28 - Convert each compound to a Fischer projection and...Ch. 28 - Prob. 28.41PCh. 28 - Prob. 28.42PCh. 28 - Prob. 28.43PCh. 28 - Prob. 28.44PCh. 28 - Prob. 28.45PCh. 28 - Draw both pyranose anomers of each aldohexose...Ch. 28 - Prob. 28.47PCh. 28 - Prob. 28.48PCh. 28 - Prob. 28.49PCh. 28 - Prob. 28.50PCh. 28 - Prob. 28.51PCh. 28 - Prob. 28.52PCh. 28 - Prob. 28.53PCh. 28 - What products are formed when each compound is...Ch. 28 - Prob. 28.55PCh. 28 - Prob. 28.56PCh. 28 - Prob. 28.57PCh. 28 - Prob. 28.58PCh. 28 - 28.58 Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.60PCh. 28 - Prob. 28.61PCh. 28 - Prob. 28.62PCh. 28 - Prob. 28.63PCh. 28 - Prob. 28.64PCh. 28 - Prob. 28.65PCh. 28 - Prob. 28.66PCh. 28 - Prob. 28.67PCh. 28 - Prob. 28.68PCh. 28 - Prob. 28.69PCh. 28 - Prob. 28.70PCh. 28 - Prob. 28.71PCh. 28 - Prob. 28.72PCh. 28 - Prob. 28.73PCh. 28 - Prob. 28.74PCh. 28 - Prob. 28.75PCh. 28 - Prob. 28.76PCh. 28 - Prob. 28.77PCh. 28 - Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.79P
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- Predict the products obtained when d-galactose reacts with each reagent.(a) Br2 and H2O (b) NaOH, H2O (c) CH3OH, H +arrow_forwardDraw the products formed when α-D-galactose is treated with each reagent: i. CH3I (excess), Ag2O ii. CH3OH, H3O+ iii. NaOH, H2O iv. Br2, H2Oarrow_forwardDraw the products formed when cholesterol is treated with each reagent. Indicate the stereochemistry around anystereogenic centers in the product.a. CH3COCIb. H2, Pd-Cc. PCCd. leic acid, H+e. [1] BH3 ·THF; [2] H2O2, -OHarrow_forward
- Which statements are correct regarding the formation of maltose?A. Hydrolysis reaction between alpha-D-glucose and beta-D-glucoseB. Condensation reaction between alpha-D-glucose and beta-D-glucoseC. Condensation reaction between beta-galactose and beta-glucoseD. Hydrolysis of starch into a di-saccharide product a). A and B b). C and D c). B and D d). B and C e). B, C and Darrow_forwardDraw Fischer projections for the product(s) formed by reaction of d-galactose with the following. In addition, state whether each product is optically active or inactive. Q.) H2/Ptarrow_forwardWhat product or products are obtained when d-galactose reacts with the following? 1. hydroxylamine/trace acid2. acetic anhydride/Δ3. HO-/H2Oarrow_forward
- Draw Fischer projections for the product(s) formed by reaction of d-ribose with the following. In addition, state whether each product is optically active or inactive Q. H2/Ptarrow_forwardWrite down the reactions: D-Glucose + HNO3 →arrow_forwardDraw Fischer projections for the product(s) formed by reaction of d-galactose with the following. In addition, state whether each product is optically active or inactive. Q.) HNO3, warmarrow_forward
- Identify the sugar in each description. a. An aldopentose that is not d-arabinose forms d-arabinitol when it is reduced with NaBH4. b. A sugar that is not D-altrose forms d-altraric acid when it is oxidized with nitric acid. c. A ketose that, when reduced with NaBH4, forms d-altritol and d-allitol.arrow_forwardDraw the structure of the expected product when monosaccharide A undergo mutarotation upon dissolving in water in the presence of Tollens reagent (AgNO3, NH4OH).arrow_forward6. Draw D-Mannose in its pyranose form.arrow_forward
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