Concept explainers
(a)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 1
Explanation of Solution
The given cyclic monosaccharide is,
Figure 2
The steps for the conversion of Haworth projection into Fischer projection are as follow:
Step 1 In the Haworth projection, if
Step-2 The substituents which are present below the ring in the Haworth projection are drawn on the right side in the Fischer projection. Similarly, the substituents which are present above the ring in the Haworth projection are drawn on the left side in the Fischer projection.
The acyclic form of given cyclic monosaccharide is,
Figure 3
The acyclic form of given cyclic monosaccharide is shown in Figure 1.
(b)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 4
Explanation of Solution
The given cyclic monosaccharide is,
Figure 5
The steps for the conversion of Haworth projection into Fischer projection are as follow:
Step 1 In the Haworth projection, if
Step-2 The substituents which are present below the ring in the Haworth projection are drawn on the right side in the Fischer projection. Similarly, the substituents which are present above the ring in the Haworth projection are drawn on the left side in the Fischer projection.
The acyclic form of given cyclic monosaccharide is,
Figure 6
The acyclic form of given cyclic monosaccharide is shown in Figure 4.
(c)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 7
Explanation of Solution
The given cyclic monosaccharide is,
Figure 8
In the chair form, if the
The substituents on a carbon are present above the plane (i.e. either equatorial or axial position) in chair form are drawn to left side in the Fischer projection and vice versa.
The acyclic form of given cyclic monosaccharide is shown below.
Figure 9
The acyclic form of given cyclic monosaccharide is shown in Figure 7.
(d)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 10
Explanation of Solution
The given cyclic monosaccharide is,
Figure 11
The steps for the conversion of Haworth projection into Fischer projection are as follow:
Step 1 In the Haworth projection, if
Step-2 The substituents which are present below the ring in the Haworth projection are drawn on the right side in the Fischer projection. Similarly, the substituents which are present above the ring in the Haworth projection are drawn on the left side in the Fischer projection.
The acyclic form of given cyclic monosaccharide is,
Figure 12
The acyclic form of given cyclic monosaccharide is shown in Figure 10.
(e)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 13
Explanation of Solution
The given cyclic monosaccharide is,
Figure 14
The steps for the conversion of Haworth projection into Fischer projection are as follow:
Step 1 In the Haworth projection, if
Step-2 The substituents which are present below the ring in the Haworth projection are drawn on the right side in the Fischer projection. Similarly, the substituents which are present above the ring in the Haworth projection are drawn on the left side in the Fischer projection.
The acyclic form of given cyclic monosaccharide is,
Figure 15
The acyclic form of given cyclic monosaccharide is shown in Figure 13.
(f)
Interpretation: The given cyclic monosaccharide is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively. The verticals bonds are represented as dashed wedge and horizontal bonds as dark wedge.
Answer to Problem 28.47P
The acyclic form of given cyclic monosaccharide is,
Figure 16
Explanation of Solution
The given cyclic monosaccharide is,
Figure 17
The steps for the conversion of Haworth projection into Fischer projection are as follow:
Step 1 In the Haworth projection, if
Step-2 The substituents which are present below the ring in the Haworth projection are drawn on the right side in the Fischer projection. Similarly, the substituents which are present above the ring in the Haworth projection are drawn on the left side in the Fischer projection.
The acyclic form of given cyclic monosaccharide is,
Figure 18
The acyclic form of given cyclic monosaccharide is shown in Figure 16.
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