Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29, Problem 29.12P
Interpretation Introduction
Interpretation:
For the given
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Show the differences between the chain-growth and step-growth mechanisms of polymerization.
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Chapter 29 Solutions
Organic Chemistry
Ch. 29.2 - Prob. 29.1PCh. 29.5 - Prob. 29.2PCh. 29.6 - Prob. AQCh. 29.6 - Prob. BQCh. 29.6 - Prob. CQCh. 29.6 - Prob. DQCh. 29.6 - Prob. EQCh. 29.6 - Prob. FQCh. 29.6 - Prob. 29.3PCh. 29.6 - Prob. 29.4P
Ch. 29 - Prob. 29.5PCh. 29 - Prob. 29.6PCh. 29 - Prob. 29.7PCh. 29 - Prob. 29.8PCh. 29 - Prob. 29.9PCh. 29 - Prob. 29.10PCh. 29 - Prob. 29.11PCh. 29 - Prob. 29.12PCh. 29 - Prob. 29.13PCh. 29 - Prob. 29.14PCh. 29 - Prob. 29.15PCh. 29 - Prob. 29.16PCh. 29 - Polycarbonates (Section 29.5C) are also formed by...Ch. 29 - Prob. 29.18PCh. 29 - Prob. 29.19PCh. 29 - Prob. 29.20PCh. 29 - Prob. 29.21PCh. 29 - Draw a structural formula of the polymer resulting...Ch. 29 - Prob. 29.23PCh. 29 - Prob. 29.24PCh. 29 - Prob. 29.25PCh. 29 - Select the monomer in each pair that is more...Ch. 29 - Prob. 29.27PCh. 29 - Prob. 29.28PCh. 29 - Prob. 29.29PCh. 29 - Prob. 29.30PCh. 29 - Prob. 29.31PCh. 29 - Prob. 29.32PCh. 29 - Prob. 29.33PCh. 29 - Radical polymerization of styrene gives a linear...Ch. 29 - Prob. 29.35PCh. 29 - Prob. 29.36PCh. 29 - Prob. 29.37PCh. 29 - Prob. 29.38P
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- Show the structure of the polymer that results from heating the following diepoxide and diamine:arrow_forwardAlthough styrene undergoes both cationic and anionic polymerization equally well, one method is often preferred with substituted styrenes. Which method is preferred with each compound? Explain.arrow_forwardWhat is the main reaction and mechanism for the polymerization of styrene? What are the side reactions?arrow_forward
- (a) Show how poly(propylene oxide) can be synthesized via anionic ring-opening polymerization. (b) Draw the mechanism for the initiation and first two propagation steps.arrow_forwardThe following two compounds form a 1 : 1 alternating copolymer. No initiator is needed for the polymerization. Propose a mechanism for formation of the copolymer.arrow_forwardProvide the mechanism for the step-growth polymerization of citric acid and ethylene glycol to form poly (ethylene glycol)-citrate. Show all steps.arrow_forward
- In a non-acid catalyzed step-growth polymerization between A-A and B-B monomers, the A groups are titratable by aqueous base (1 N) and [A-A] [B-B) = 6 mol.kg-1. a) What is the DP if it takes 100 mL of base to neutralize the reaction mixture at 700 minutes of reaction time (assuming the initial total weight 500 g)?...arrow_forwardRadical polymerization of styrene gives a linear polymer. Radical polymerization of a mixture of styrene and 1,4-divinylbenzene gives a cross-linked network polymer of the type shown in Figure 29.1. Show by drawing structural formulas how incorporation of a few percent of 1,4-divinylbenzene in the polymerization mixture gives a cross-linked polymer.arrow_forwardCommercial polyisobutylene (PIB or butyl rubber) is synthesized via cationic polymerization. Explain why it cannot be made through free radical or anionic polymerizationarrow_forward
- Briefly discuss emulsion and suspension polymerization techniques.arrow_forwarda copolymer is made up of 40.01% polystyrene 20.38% acrylonyl and 31.51% polybutadiene a) Calculate the Molar Fraction b) the Degree of Polymerization if there is a weight of 320, 000 gr of copolymer c) carry out the polymerization reaction d) What is the name of this polymer and e) Mention some applications of some monomerarrow_forwardWhat is anionic polymerization ?arrow_forward
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