Pearson eText for Biochemistry: Concepts and Connections -- Instant Access (Pearson+)
Pearson eText for Biochemistry: Concepts and Connections -- Instant Access (Pearson+)
2nd Edition
ISBN: 9780137533114
Author: Dean Appling, Spencer Anthony-Cahill
Publisher: PEARSON+
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Chapter 3, Problem 10P

Suppose a reaction has Δ Ho and Δ So values independent of temperature (i.e., assume these values are constant over some range of temperature). Show from this, and the equations given in this chapter, that ln K = -ΔH o RT + ΔS o R where K is the equilibrium constant. How could you use values of K determined at different temperatures to determine ΔH o for the reaction? (Hint. Recall that you are treating ΔH o and ΔS o as constants.)

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For a particular reaction, AH° = −16.1 kJ/mol and AS° = −21.8 J/(mol·K). Assuming these values change very little with temperature, at what temperature does the reaction change from nonspontaneous to spontaneous in the forward direction? OT= Is the reaction in the forward direction spontaneous at temperatures greater than or less than the calculated temperature? less than greater than K
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