Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
expand_more
expand_more
format_list_bulleted
Question
Chapter 3, Problem 3.30P
Interpretation Introduction
(a)
Interpretation:
The bonding and antibonding MOs of the
Concept introduction:
When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.
Interpretation Introduction
(b)
Interpretation:
The symmetries of the two MOs resulting from the overlap shown are to be determined.
Concept introduction:
When the overlap of two orbitals is along the bond axis, the MO has
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The bond in Cl2 can be explained by the end-on overlap between two p AOs, as shown inthis diagram.
(a) Draw the bonding and antibonding MOs that would result from such an interaction.
(b) What is the symmetry of each of these MOs?
Draw the MO diagram of linear NO2 by consulting the character tables and orbital energies, and to align your O/N/O axes. Remember to use a lower symmetry point group for the linear molecule. What is the bond order of linear NO2? How does it change if you make it NO2 - or NO2 +. Draw each SALC and look for interactions between the orbitals.
Draw the complete MO diagram for [CoCl6]4-
Label the AOs and SALCs and MOs.
Draw a sketch for each MO with the appropriate symmetry label
Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.1YTCh. 3 - Prob. 3.2YTCh. 3 - Prob. 3.3YTCh. 3 - Prob. 3.4YTCh. 3 - Prob. 3.5YTCh. 3 - Prob. 3.6YTCh. 3 - Prob. 3.7YTCh. 3 - Prob. 3.8YTCh. 3 - Prob. 3.9YTCh. 3 - Prob. 3.10YTCh. 3 - Prob. 3.11YTCh. 3 - Prob. 3.12YTCh. 3 - Prob. 3.13YT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw structures for the following showing correct geometry and identify all of the symmetry elements present ) ClO-.arrow_forwardWhich MOs are the HOMO and the LUMO in the excited state?arrow_forwardBased on the shapes of p and d orbitals and the necessary match of symmetry,please predict and sketch all of the possible orbital interactions between the porbitals of atom A and the d orbitals of atom B for the formation of bonding andantibonding orbitals?arrow_forward
- Which of the following do not have a plane of symmetry?arrow_forwardDraw the distributioon oof a metal when it is in a octahedral field. determine the symmetry corresponding too each orbitalarrow_forwardUsing appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i) C4 (ii) σh (iii) S4.arrow_forward
- I am confused why this powerpoint slight says 'sideways overlap... leads to a p-bonding MO AND a p*-antibonding MO.' Isn't it one or the other? Why does it say AND? The orbitals can't have descrutive and constructive interaction at the same time right?arrow_forwardUsing symmetry, TOM and Orbital energy table Atomic, construct the OM Diagram for the following molecule : SCl 2 Identify nonbinding OMs and HOMO and LUMO.arrow_forwardAbout the special type of hybridization involved in complexation (all are correct except Select one: 1- in case of d2sp3 hybridization trigonal (square planner) shape complex is obtained while in case of dsp2 hybridization a hexagonal shape complex is obtained 2- dsp2 hybridization is obtained when the transient metal orbitals d orbitals , one S and 2 p orbitals are mixed together to obtain six equivalent d2sp3 orbitals forming a hexagonal shape complex 3- in case of six guests containing complex like ormaplatine d2sp3 hybridization is encountered while in case of cisplatin dsp2 hybridization is encountered 4- d2sp3 hybridization is obtained when the transient metal orbitals 2 d orbitals , one S and 3 p orbitals are mixed together to obtain six equivalent d2sp3 orbitals forming a hexagonal shape complexarrow_forward
- Molecules of AsF3 are polar while molecules of AsF5 are not. Use a symmetry argument to explain why. Note: Please briefly explain, Thank you.arrow_forwarda-Draw a molecular orbital (MO) energy level diagram for NO. Label the atomic orbitals, MOs and identify the frontier orbitals. b-Explain the differences in bond dissociation energies and bond lengths on addition and removalof an electron from NO.arrow_forwardExplain why 1g is the ground state for H2+ . By combining your answer with the answer to Problem 5, what conclusions can you draw about the molecular orbital description of the bond in H2+ ?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Linear Combination of Atomic Orbitals LCAO; Author: Edmerls;https://www.youtube.com/watch?v=nq1zwrAIr4c;License: Standard YouTube License, CC-BY
Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY