General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 3, Problem 3.86EP

(a)

Interpretation Introduction

Interpretation:

The number of unpaired electrons that is associated with electronic configuration 1s22s22p5 has to be given.

Concept Introduction:

Electronic configuration of an atom describes how many electrons are present in the shell.  Many orbitals are present about the nucleus of an atom.  In these orbitals the electrons do not occupy randomly.  There are three rules for assigning the electrons to various shells, subshells, and orbitals.  They are,

  • The subshells are filled in increasing order of energy.
  • In a subshell, the electrons occupy the orbital singly first in all orbitals before pairing up by the second electron.  All the electrons that are in singly occupied orbitals have same spin.
  • In a given orbital there cannot be more than two electrons and they have opposite spins.

Electronic configuration of an element is the one that gives information about how many electrons are present in each electron subshell of an atom.  The electrons are added to the subshells in increasing order of energy.  Electronic configurations are written in shorthand notation which uses a number‑letter combination.  The shell is indicated by the number and subshell is indicated by the letter.  Superscript that follows the subshell tells how many electrons are present in the subshell.

The order of filling up the electrons in the subshell is done as shown in the given figure below.

General, Organic, and Biological Chemistry, Chapter 3, Problem 3.86EP , additional homework tip  1

Orbital diagram is the one that gives information about the number of electrons present in the electron orbitals of an atom.  The difference between electronic configuration and orbital diagram is that electronic configuration deals with the electrons occupancy in the subshell while orbital diagram deals with the electrons occupancy in the electron orbital.  Electrons are paired up in the orbital only when all the orbitals in the subshell are singly filled.

(b)

Interpretation Introduction

Interpretation:

The number of unpaired electrons that is associated with electronic configuration 1s22s22p63s1 has to be given.

Concept Introduction:

Electronic configuration of an atom describes how many electrons are present in the shell.  Many orbitals are present about the nucleus of an atom.  In these orbitals the electrons do not occupy randomly.  There are three rules for assigning the electrons to various shells, subshells, and orbitals.  They are,

  • The subshells are filled in increasing order of energy.
  • In a subshell, the electrons occupy the orbital singly first in all orbitals before pairing up by the second electron.  All the electrons that are in singly occupied orbitals have same spin.
  • In a given orbital there cannot be more than two electrons and they have opposite spins.

Electronic configuration of an element is the one that gives information about how many electrons are present in each electron subshell of an atom.  The electrons are added to the subshells in increasing order of energy.  Electronic configurations are written in shorthand notation which uses a number‑letter combination.  The shell is indicated by the number and subshell is indicated by the letter.  Superscript that follows the subshell tells how many electrons are present in the subshell.

The order of filling up the electrons in the subshell is done as shown in the given figure below.

General, Organic, and Biological Chemistry, Chapter 3, Problem 3.86EP , additional homework tip  2

Orbital diagram is the one that gives information about the number of electrons present in the electron orbitals of an atom.  The difference between electronic configuration and orbital diagram is that electronic configuration deals with the electrons occupancy in the subshell while orbital diagram deals with the electrons occupancy in the electron orbital.  Electrons are paired up in the orbital only when all the orbitals in the subshell are singly filled.

(c)

Interpretation Introduction

Interpretation:

The number of unpaired electrons that is associated with electronic configuration 1s22s22p63s23p1 has to be given.

Concept Introduction:

Electronic configuration of an atom describes how many electrons are present in the shell.  Many orbitals are present about the nucleus of an atom.  In these orbitals the electrons do not occupy randomly.  There are three rules for assigning the electrons to various shells, subshells, and orbitals.  They are,

  • The subshells are filled in increasing order of energy.
  • In a subshell, the electrons occupy the orbital singly first in all orbitals before pairing up by the second electron.  All the electrons that are in singly occupied orbitals have same spin.
  • In a given orbital there cannot be more than two electrons and they have opposite spins.

Electronic configuration of an element is the one that gives information about how many electrons are present in each electron subshell of an atom.  The electrons are added to the subshells in increasing order of energy.  Electronic configurations are written in shorthand notation which uses a number‑letter combination.  The shell is indicated by the number and subshell is indicated by the letter.  Superscript that follows the subshell tells how many electrons are present in the subshell.

The order of filling up the electrons in the subshell is done as shown in the given figure below.

General, Organic, and Biological Chemistry, Chapter 3, Problem 3.86EP , additional homework tip  3

Orbital diagram is the one that gives information about the number of electrons present in the electron orbitals of an atom.  The difference between electronic configuration and orbital diagram is that electronic configuration deals with the electrons occupancy in the subshell while orbital diagram deals with the electrons occupancy in the electron orbital.  Electrons are paired up in the orbital only when all the orbitals in the subshell are singly filled.

(d)

Interpretation Introduction

Interpretation:

The number of unpaired electrons that is associated with electronic configuration 1s22s22p63s23p64s23d5 has to be given.

Concept Introduction:

Electronic configuration of an atom describes how many electrons are present in the shell.  Many orbitals are present about the nucleus of an atom.  In these orbitals the electrons do not occupy randomly.  There are three rules for assigning the electrons to various shells, subshells, and orbitals.  They are,

  • The subshells are filled in increasing order of energy.
  • In a subshell, the electrons occupy the orbital singly first in all orbitals before pairing up by the second electron.  All the electrons that are in singly occupied orbitals have same spin.
  • In a given orbital there cannot be more than two electrons and they have opposite spins.

Electronic configuration of an element is the one that gives information about how many electrons are present in each electron subshell of an atom.  The electrons are added to the subshells in increasing order of energy.  Electronic configurations are written in shorthand notation which uses a number‑letter combination.  The shell is indicated by the number and subshell is indicated by the letter.  Superscript that follows the subshell tells how many electrons are present in the subshell.

The order of filling up the electrons in the subshell is done as shown in the given figure below.

General, Organic, and Biological Chemistry, Chapter 3, Problem 3.86EP , additional homework tip  4

Orbital diagram is the one that gives information about the number of electrons present in the electron orbitals of an atom.  The difference between electronic configuration and orbital diagram is that electronic configuration deals with the electrons occupancy in the subshell while orbital diagram deals with the electrons occupancy in the electron orbital.  Electrons are paired up in the orbital only when all the orbitals in the subshell are singly filled.

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Chapter 3 Solutions

General, Organic, and Biological Chemistry

Ch. 3.3 - Prob. 1QQCh. 3.3 - Prob. 2QQCh. 3.3 - What is the atomic mass of a hypothetical element...Ch. 3.3 - The element chlorine, which has two isotopic...Ch. 3.4 - Based on periodic table location, which pair of...Ch. 3.4 - Prob. 2QQCh. 3.4 - Prob. 3QQCh. 3.4 - Which of the following pieces of information about...Ch. 3.4 - Prob. 5QQCh. 3.5 - Prob. 1QQCh. 3.5 - Prob. 2QQCh. 3.5 - Prob. 3QQCh. 3.5 - Prob. 4QQCh. 3.6 - Prob. 1QQCh. 3.6 - Prob. 2QQCh. 3.6 - The maximum number of electrons that an electron...Ch. 3.6 - Prob. 4QQCh. 3.6 - Prob. 5QQCh. 3.6 - How many electrons can a 3d subshell accommodate?...Ch. 3.6 - Prob. 7QQCh. 3.7 - An electron configuration is a statement of how...Ch. 3.7 - How many electrons are present in atoms of the...Ch. 3.7 - The correct electron configuration for atoms of...Ch. 3.7 - Which of the following statements is consistent...Ch. 3.7 - Prob. 5QQCh. 3.7 - How many unpaired electrons are presents in the...Ch. 3.8 - Prob. 1QQCh. 3.8 - Prob. 2QQCh. 3.8 - Which of the following elements is located in the...Ch. 3.8 - Prob. 4QQCh. 3.9 - Which of the following elements is a noble-gas...Ch. 3.9 - Which of the following element-classification...Ch. 3.9 - Prob. 3QQCh. 3 - Indicate which subatomic particle (proton,...Ch. 3 - Prob. 3.2EPCh. 3 - Indicate whether each of the following statements...Ch. 3 - Indicate whether each of the following statements...Ch. 3 - How many protons, neutrons, and electrons are...Ch. 3 - Prob. 3.6EPCh. 3 - Prob. 3.7EPCh. 3 - Prob. 3.8EPCh. 3 - Prob. 3.9EPCh. 3 - What is the atomic number for atoms composed of...Ch. 3 - Prob. 3.11EPCh. 3 - Prob. 3.12EPCh. 3 - Prob. 3.13EPCh. 3 - What is the total number of nucleons present for...Ch. 3 - What is the total number of charged subatomic...Ch. 3 - What is the total number of charged subatomic...Ch. 3 - Prob. 3.17EPCh. 3 - What is the total charge (including sign)...Ch. 3 - Complete the following table by filling in the...Ch. 3 - Complete the following table by filling in the...Ch. 3 - An atom with an number of 11 contains 36 subatomic...Ch. 3 - An atom with an atomic number of 17 contains 52...Ch. 3 - Prob. 3.23EPCh. 3 - Determine the following information for an atom...Ch. 3 - Prob. 3.25EPCh. 3 - Prob. 3.26EPCh. 3 - The atomic number of the element carbon (C) is 6....Ch. 3 - The atomic number of the element sulfur (S) is 16....Ch. 3 - The following are selected properties of the most...Ch. 3 - The following are selected properties of the most...Ch. 3 - Calculate the atomic mass of each of the following...Ch. 3 - Calculate the atomic mass of each of the following...Ch. 3 - The element copper (Cu) has an atomic mass of...Ch. 3 - The element lithium (Li) has an atomic mass of...Ch. 3 - Using the information given in the following...Ch. 3 - Using the information given in the table in...Ch. 3 - Prob. 3.37EPCh. 3 - Indicate whether each of the following statements...Ch. 3 - Prob. 3.39EPCh. 3 - Indicate whether each of the following numbers are...Ch. 3 - Write the complete chemical symbol (EZA) for the...Ch. 3 - Write the complete chemical symbol (EZA) for the...Ch. 3 - Prob. 3.43EPCh. 3 - Prob. 3.44EPCh. 3 - Prob. 3.45EPCh. 3 - Prob. 3.46EPCh. 3 - Based on periodic table position, select the two...Ch. 3 - Based on periodic table position, select the two...Ch. 3 - Prob. 3.49EPCh. 3 - Prob. 3.50EPCh. 3 - How many elements exist with an atomic number less...Ch. 3 - How many elements exist with an atomic number...Ch. 3 - Prob. 3.53EPCh. 3 - Prob. 3.54EPCh. 3 - With the help of the periodic table, write...Ch. 3 - With the help of the periodic table, write...Ch. 3 - Prob. 3.57EPCh. 3 - Prob. 3.58EPCh. 3 - Prob. 3.59EPCh. 3 - Identify the nonmetal in each of the following...Ch. 3 - Prob. 3.61EPCh. 3 - Classify each of the following general physical...Ch. 3 - Prob. 3.63EPCh. 3 - Determine the following, using the periodic table...Ch. 3 - Which of the six elements nitrogen, beryllium,...Ch. 3 - Prob. 3.66EPCh. 3 - Prob. 3.67EPCh. 3 - Prob. 3.68EPCh. 3 - How many electrons can be accommodated in each of...Ch. 3 - How many electrons can be accommodated in each of...Ch. 3 - Prob. 3.71EPCh. 3 - Prob. 3.72EPCh. 3 - Prob. 3.73EPCh. 3 - How many electron orbitals are there of each of...Ch. 3 - Indicate whether each of the following statements...Ch. 3 - Indicate whether each of the following statements...Ch. 3 - Write complete electron configurations for atoms...Ch. 3 - Write complete electron configurations for atoms...Ch. 3 - Prob. 3.79EPCh. 3 - On the basis of the total number of electrons...Ch. 3 - Write complete electron configurations for atoms...Ch. 3 - Write complete electron configurations for atoms...Ch. 3 - Draw the orbital diagram associated with each of...Ch. 3 - Draw the orbital diagram associated with each of...Ch. 3 - How many unpaired electrons are present in each of...Ch. 3 - Prob. 3.86EPCh. 3 - The electron configuration of the isotope 16O is...Ch. 3 - The electron configuration of the isotope 24Mg is...Ch. 3 - Write electron configurations for the following...Ch. 3 - Write electrons configurations for the following...Ch. 3 - Indicate whether the elements represented by the...Ch. 3 - Prob. 3.92EPCh. 3 - Prob. 3.93EPCh. 3 - Specify the location of each of the following...Ch. 3 - For each of the following elements, specify the...Ch. 3 - For each of the following elements, specify the...Ch. 3 - Prob. 3.97EPCh. 3 - Prob. 3.98EPCh. 3 - Classify each of the following elements as a noble...Ch. 3 - Classify each of the following elements as a noble...Ch. 3 - Prob. 3.101EPCh. 3 - Prob. 3.102EPCh. 3 - Classify the element with each of the following...Ch. 3 - Classify the element with each of the following...
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