PHYSICS F./SCI... W/MOD V.II W/KIT
PHYSICS F./SCI... W/MOD V.II W/KIT
4th Edition
ISBN: 9780134819884
Author: GIANCOLI
Publisher: PEARSON
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Chapter 38, Problem 34P

(a)

To determine

The wavelength of electron in free space.

(b)

To determine

The wavelength of electron when over the well.

(c)

To determine

The diagram showing potential energy and total energy as function of x and a wave function.

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(10) i) Use the quantum mechanical kinetic energy operator T, = to find the kinetic energy of the first 2m dx? excited state of the Particle in a Box (with n = 2). ii) Then, use the relationship of kinetic energy and momentum (KE = p?/2m) to find an equation for the de Broglie wavelength of the particle in a one-dimensional box as a function only of the box length L and quantum number n. iii) Sketch the wavefunction in the box to verify that the expression you obtained in part ii) is correct.
2) The energy levels of a quantum-mechanical, one-dimensional, anharmonic oscillator maybe approximated as 2 =(n * (n + )' En hw ;n = 0,1,2,... (++) = The parameter x, usually « 1, represents the degree of anharmonicity. Show that, to the first order in x and the fourth order in u (= ħw/kgT), the specific heat of a system of N such oscillators is given by C = Nk [(1-u² + *)+ 4x (: + *)]. 240 80 Note that the correction term here increases with temperature.
What do we need to do to average over Θ and ф to get the probability that the electron is inside a shell of radius r and thickness dr?

Chapter 38 Solutions

PHYSICS F./SCI... W/MOD V.II W/KIT

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