Organic Chemistry
4th Edition
ISBN: 9780077479824
Author: SMITH, Janice Gorzynski/
Publisher: McGraw-Hill College
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Chapter 4, Problem 4.2P
Interpretation Introduction
Interpretation: The hydrocarbon that is not another representation of
Concept Introduction: The identification of a hydrocarbon that is another representation of a given hydrocarbon or not, is done through checking the number and position of branched carbon and the number of carbon atoms that are placed in a row.
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Is there any difference between 2-methylpropane and isobutane? Why is the structure in the image not named 2-methylpropane but isobutane. What is meant by "iso"?
1 Which of the following has(have) the same molecular formula as hexane? A. 3-ethylpentane
B. 2,4-dimethylpentane
C. 3,3-dimethylpentane
D. 2,3-dimethylpentane
E. 2,3-dimethylbutane
1b.
Which of these formulas is(are) not theoretically possible? A. C6H6
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1c.
Which of these formulas is(are) not valid for hexane?
A. C6H14
B. C6H6C. C6H16D. CH3CH2CH2CH2CH2CH3
E. CH3(CH2)4CH3
a. Which of the following compounds have the same empirical formula?(1) But-2-ene(2) Propane(3) EtheneA. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)
b. Which of the following statements concerning homologous series is INCORRECT?A. Members of a series have identical chemical properties.B. Members of a series have the same general formula.C. Each member differs from the next by a −CH2− group.D. Members of a series show a gradual change of physical properties.
Chapter 4 Solutions
Organic Chemistry
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Explain why two different straight-chain alkanes could not be constitutional isomers.arrow_forward(a) What structural feature is associated with each type of hydrocarbon: alkane, cycloalkane, alkene, and alkyne?(b) Give the general formula for each type.(c) Which hydrocarbons are considered saturated?arrow_forwarda. Candle wax contains an alkane with 28 carbon atoms per molecule. What is the molecular formula of this alkane?A. C28H54B. C28H56C. C28H58D. C28H60 b. Which of the following might be the respective relative molecular masses of four consecutive members of a homologous series?(Relative atomic masses: H = 1.0, C = 12.0, O = 16.0)A. 32, 46, 60, 74B. 26, 38, 50, 62C. 28, 38, 48, 58D. 44, 57, 70, 83arrow_forward
- Referring to question 10 of the handout: Butanal (MW= 72) has a boiling point of 76 °C while butanol (MW= 74) has a boiling point of 118 °C. What accounts for this difference in boiling points?arrow_forwardWhat are ALL the types of intermolecular bonding does n-pentane have? What are ALL the types of intermolecular bonding does 1-butane have?arrow_forwardAn alkane with 4 carbon atoms would have how many hydrogen atoms in each molecule Select one: a. 8 b. 10 c. 4 d. 16arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
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