Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
expand_more
expand_more
format_list_bulleted
Question
Chapter 4, Problem 4.38E
Interpretation Introduction
Interpretation:
The relation
Concept introduction:
The Maxwell relations are the equations showing the relation between the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Calculate V−1(∂V/∂T)p,n for an ideal gas?
1. Determine the work done in an isothermal, reversible expansion of a real gas obeying the virial
equation of state, PV = A + BP + CP².
Since we will be dealing with partial derivatives later in the semester, this is a good opportunity to review this topic (see appendix C). Then evaluate the following partial derivatives
(a) PV = nRT; (∂ P/∂V)T
(b) r = (x2 + y2 + z 2 )1/2; (∂ r/∂y)x,z
Chapter 4 Solutions
Physical Chemistry
Ch. 4 - List the sets of conditions that allow dS, dU, and...Ch. 4 - Explain why conditions for using S>0 as a strict...Ch. 4 - Explain how the equation dU+pdVTdS0 is consistent...Ch. 4 - Explain why the spontaneity conditions given in...Ch. 4 - Prove that the adiabatic free expansion of an...Ch. 4 - Derive equation 4.6 from equation 4.5.Ch. 4 - Derive equation 4.8 from equation 4.7.Ch. 4 - The third part of equation 4.9 mentions a...Ch. 4 - Calculate A for a process in which 0.160mole of an...Ch. 4 - What is the maximum amount of non-pV work that can...
Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35ECh. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Prob. 4.39ECh. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60ECh. 4 - Prob. 4.61ECh. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71ECh. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73ECh. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75ECh. 4 - Prob. 4.76E
Knowledge Booster
Similar questions
- What are the numerical values of the heat capacities c-v and c-p of a monatomic ideal gas,in units of cal/mol.K and L.atm/mol.K?arrow_forwardIn the equation w = P V, why is there a negative sign?arrow_forwardA 0.250 mol nitrogen initially at 50 °C with a volume of 8.00 L is allowed to expand reversibly and adiabatically until its volume has doubled. Calculate the value of ΔHwhen Cp = 7/2R.arrow_forward
- (a) Express (∂Cp/∂P)T as a second derivative of H and find its relation to (∂H/∂P)T. (b) From the relationships found in (a), show that (∂Cp/∂V)T=0 for a perfect gas.arrow_forwardA sample of 2.2 mol CO2(g) is originally confined in 15 dm3 at 280 K and then undergoes adiabatic expansion against a constant pressure of 78.5 kPa until the volume has increased by a factor of 4.0. Calculate ΔT. (The final pressure of the gas is not necessarily 78.5 kPa.)arrow_forwardHow much work is done in blowing up a balloon from zero volume to a volume of 6.7 L, assuming that p = 1.00 bar and no work is required to stretch the rubber? (In reality, the work that goes into stretching the rubber is substantial.)arrow_forward
- Assume N₂ behaves as perfect gas. It expands reversibly and adiabatically from Vi to Vf with the pressure change from pi to pf. (a) Derive the temperature versus volume relationship and the pressure and volume relationship for this expansion. (b) When a sample of N₂ of mass 3.12 g at 23.0 °C is allowed to expand reversibly and adiabatically from 4.00 × 10² cm3 to 2.00 dm3, what is the work done by the gas?arrow_forwardCalculate the work done by a gas w hen it expandsthrough (a) 1.0 cm3, (b) 1.0 dm3 against an atmospheric pressure of 100 kPa . What work must be done to compress thegas back to original state in each case?arrow_forwardP3A.2 A sample consisting of 0.10 mol of perfect gas molecules is held by a piston inside a cylinder such that the volume is 1.25 dm²; the external is constant at 1.00 bar and the temperature is maintained at 300 Kby a thermostat. The piston is released so that the gas can expand. Calculate (a) the volume of the gas when the expansion is complete; (b) the work done when the gas expands; (c) the heat absorbed by the system. Hence calculate ASor pressurearrow_forward
- Nitesharrow_forwardA sample of argon of mass 6.56 g occupies 18.5 dm3 at 305 K.(i) Calculate the work done when the gas expands isothermally against a constant external pressure of 7.7 kPa until its volume has increased by 2.5 dm3. (ii) Calculate the work that would be done if the same expansion occurred reversibly.arrow_forward2. Given the equation S, - S, = dq use appropriate thermodynamic equations T V. to show that S, -S, = nC, In |+ nC, In Pi V,arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning