The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn. Concept introduction: Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer. Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space. Enantiomers: A compound which is non-superimposable mirror image is called enantiomers. Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers. Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer) .

Question

Are the following pairs identical, enantiomers, diastereomers, or constitutional isomers?

Answer 1

Question

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

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Answer 2

Question

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

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Answer 3

Question

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

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Answer 4

Question

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

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Answer 5

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 6

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 7

Chapter 4, Problem 62P

(a)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given pairs of compound identical, enantiomers, diastereomers, or constitutional isomers have to be drawn.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 14

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Answer 25

Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Prob. 6P Ch. 4.2 - Prob. 7P Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.

Solution Summary: Concept introduction: Isomer is a molecule having the same molecular formula but with different chemical structure.

Concept explainers

Chapter 4 Solutions