Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Textbook Question
Chapter 5, Problem 11E
Use curved arrows to show the most likely acid-base reaction between phenol and NaOH.
a. Use
b. Calculate
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H
A
1. KCN, H,O
2. NaBH4, MeOH
3. cyclopentanone
TSOH, benzene
heat
o look for
B
Ph
Ph-
C
D
Ph
OH
Given these reactions, answer the questions (one answer can be used twice)
NaOEt
1
YBr
EtOH
YBr
Br
KOtBu
||
|||
Br
IV
Reaction I is most likely
Reaction II is most likely
Reaction III is most likely
Reaction IV is most likely
NaCN
✓ [Choose]
E2
E1
SN1
SN2
[Choose]
[Choose ]
19. Choose the correct reagents/reactants to synthesize the following compound.
1. NaH
1. NaH
A.
OH 2.
OH 2.
Br
Br
3. H3O*
С.
1. NaH
1. NaH
HO
2.
HO
2.
Br
Br
3. H;0*
B.
D.
Chapter 5 Solutions
Custom eBook for Organic Chemistry
Ch. 5 - Which elements on the periodic table (other than...Ch. 5 - You will not find “hydroxide” in the stockroom,...Ch. 5 - Prob. 3CTQCh. 5 - Prob. 4CTQCh. 5 - Prob. 5CTQCh. 5 - Prob. 6CTQCh. 5 - On which do you expect to have a more intense and...Ch. 5 - Prob. 8CTQCh. 5 - Prob. 9CTQCh. 5 - Prob. 10CTQ
Ch. 5 - Prob. 11CTQCh. 5 - Prob. 12CTQCh. 5 - Prob. 13CTQCh. 5 - Prob. 14CTQCh. 5 - Prob. 15CTQCh. 5 - Prob. 16CTQCh. 5 - For each proposed set of resonance structures: a....Ch. 5 - Consider the polarization of the C=O bond in the...Ch. 5 - The C=O double bond is called a “carbonyl bond.”...Ch. 5 - Prob. 20CTQCh. 5 - Prob. 21CTQCh. 5 - Prob. 22CTQCh. 5 - Prob. 23CTQCh. 5 - Prob. 24CTQCh. 5 - Prob. 25CTQCh. 5 - Prob. 26CTQCh. 5 - Prob. 27CTQCh. 5 - Prob. 28CTQCh. 5 - Prob. 29CTQCh. 5 - Prob. 30CTQCh. 5 - Prob. 31CTQCh. 5 - Confirm that there is no legitimate Lewis...Ch. 5 - Draw all resonance structures of the molecule...Ch. 5 - Prob. 34CTQCh. 5 - Prob. 35CTQCh. 5 - Prob. 36CTQCh. 5 - Occasionally, we will see an ionic compound that...Ch. 5 - Prob. 2ECh. 5 - Prob. 3ECh. 5 - Prob. 4ECh. 5 - Is it possible to draw a resonance structure of...Ch. 5 - Prob. 6ECh. 5 - Prob. 7ECh. 5 - Prob. 8ECh. 5 - Phenol (shown below) has a pKa10 . a. Based on pKa...Ch. 5 - Use curved arrows to show the most likely...Ch. 5 - Prob. 12ECh. 5 - Complete each Lewis structure, draw all important...Ch. 5 - Use curved arrows to show the most likely...Ch. 5 - Construct an explanation for why sulfuric acid is...Ch. 5 - Prob. 16ECh. 5 - Prob. 17ECh. 5 - Prob. 18E
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- Complete the given reactions. Add hydrogen atoms and charges to the appropriate atoms. Reaction A H₂C-CH₂-C -NCH, + NaOH H H₂C-CH₂-C-N-CH₂ + HCI H heat 2 heat Incorrect Reaction B OH Y H₂C 0 Na H₂N CH₂ H₂C OH H₂N CH₂arrow_forwardChoose the correct product for each reaction. A. B. C. D. PPh3 H PPh3 || I ။arrow_forward3. What are the products of the following reaction? H,O 4. Write in the product of this reaction: H;O Benzonitrile heatarrow_forward
- HO. OH NH2 Reactant A Reactant B A "Hydrazone"arrow_forwardGiven each value, determine whether the starting material or product is favored at equilibrium. a.Keq = 0.5 b.ΔGo = −100 kJ/mol c.ΔHo = 8.0 kJ/mol d.Keq = 16 e. ΔGo = 2.0 kJ/mol f.ΔHo = 200 kJ/mol g. ΔSo = 8 J/(K•mol) h.ΔSo = −8 J/(K•mol)arrow_forward1) Write A, B, C for the following reactions B heat CO₂ OEt 1) NaOEt/EtOH 2) A Br aq NaOH 2)H,0* Barrow_forward
- FO 8 2. 3. H₂O*/H₂O 1. NaOEt, EtOH 2. H3O+arrow_forwardDraw the major organic product for each of the hydroboration-oxidation reactions. Disregard stereochemistry. Draw the product of Reaction A. Select Draw Rings More Erase H B Reaction A. 1. B2H6 2. H2О2 (аq) ЗM NaOHarrow_forwardBr KO Bu (one equivalent) t-BuOHarrow_forward
- Label each statement as True or False. a. CH3CH2+ is the conjugate acid of CH2=CH2. b.CH3CH2− is the conjugate base of CH3CH2+. c. CH2=CH2 is the conjugate base of CH3CH2−. d. CH2=CH− is the conjugate base of CH2=CH2. e. CH3CH3 is the conjugate acid of CH3CH2−.arrow_forwardComplete the following reaction COOH NO,arrow_forwardFor the following reactions, predict the likely product(s) of the reaction or write 'no reaction." Me H Me °x Me Me Me Br Me Me Me Nal, NaOCI EtOH, H₂O HNO3 ACOH AICI 3arrow_forward
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