Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 5, Problem 30CTQ
Interpretation Introduction

Interpretation: The reason that explains benzene and other aromatic molecule has low potential energy should be determined.

Concept introduction: When one single structure is unable to describe all the properties of single molecule, a phenomenon called resonance comes into play. This arises when two or more than two Lewis structures are possible for one molecule. All such structures are called resonating structures and have same placement of atoms in them but these have different locations of bond pairs and lone pairs. The resonating structures are inter-convertible with each other. The resultant of all the resonating or contributing structures is called the resonance hybrid.

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Refer to the attached picture for the following questions Which among the five aromatic molecules will have the least ability to undergo molecular stacking?Which aromatic structures contain functional groups which are electron-withdrawing?
What is Resonance Theory? Sate five conclusions that can be drawn from the theory. State the two main experiments that were used to establish the extra stability of the benzene molecule. What are the factors that confer Aromaticity to an organic molecule? i. State the effects of substituents on a benzene derivative towards further aromatic substitution.  Based on the above suggest the various types of substituents that can be attached to Benzene. What are the various ways by which alkenes may be synthesized? i. Give two examples each of Unsymmetrical alkenes and reagents. Give two examples of reactions of alkenes that result in Anti-Markonikov’s addition products
Determine if the following compounds are aromatic, non-aromatic, or anti-aromatic. Show a structure that helps to support your classification. This structure should not just redraw the compound; show lone pairs, resonance, and/or contributing π bonds as part of your explanation.

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