(a) Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified. Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R , S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 1

Question

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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a) Draw Haworth projections of both - and -anomers of D-fructose. Indicate which carbon is the anomeric carbon.b) Sucrose is a disaccharide made up of a molecule of D-fructose and D-glucose. Draw the structure of sucrose clearly indicating the linkage between the two monosaccharides and its biological significance.c) Tollen’s reagent is a very mild oxidizing agent which normally oxidize aldehydes but not ketones. However, both glucose and fructose give positive results with Tollen’s reagent and are classified as reducing sugars. Explain how fructose can also give positive results with Tollen’s reagent (illustrate using structures).

The following trisaccharide derivative is important to human health.The A ring is ?-deoxy?

A) Define "reducing sugar." (b) Sucrose is a disaccharide composed of glucose and fructose (Glc(1 → 2)Fru). Explain why sucrose is not a reducing sugar, even though both glucose and fructose are.

Answer 2

Question

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 3

Question

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 4

Question

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

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Answer 5

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 6

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 7

Chapter 5, Problem 5.59P

Interpretation Introduction

(a)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 8

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 9

Interpretation Introduction

(b)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 10

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 11

Interpretation Introduction

(c)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 12

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 13

Interpretation Introduction

(d)

Interpretation: The relationship between simple sugar D-erythrose and the given compound as enantiomers, diastereomers, or identical is to be identified.

Concept introduction: The stereocenters are carbon atoms on which the interchanging of two atoms or groups results in the formation of new stereoisomers. The stereocenters are also known as stereogenic centers. R,S configurations can be used to determine the relation between the two compounds. Enantiomer of a compound has opposite configuration. Diastereomers of a compound have at least one stereogenic centre with same configuration and at least one with opposite configuration.

Answer 14

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Answer 15

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Answer 17

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Draw the mirror image of each compound. Label each...Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - The facts in section 5.4A can be used to locate...Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains the relationship between simple sugar D-erythrose and the given compound as an enantiomer, diastereomers, or identical.

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