Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
2nd Edition
ISBN: 9780134777559
Author: Tro, Nivaldo J.
Publisher: PEARSON
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Chapter 5, Problem 67E
Interpretation Introduction
To determine: The geometry about each interior atom in each molecule and draw the molecule
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Determine the geometry about each interior atom in each molecule and draw the molecule. (Skeletal structure is indicated in parentheses.)a. CH3OH (H3COH)b. CH3OCH3 (H3COCH3)c. H2O2 (HOOH)
Determine the geometry about each interior atom in each molecule and draw the molecule. (Skeletal structure is indicated in parentheses.)a. CH3NH2 (H3CNH2)b. CH3CO2CH3 (H3CCOOCH3 both O atoms attached to second C)c. NH2CO2H (H2NCOOH both O atoms attached to C)
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Determine the Steric Number around the central atom = number of atoms + lone pairs
Determine the geometry of these electron pairs (including the lone pairs)
Determine the molecular geometry by ignoring the lone pairs.
Draw a 3D sketch of the molecule and make a model.
OPCL3
BrF3
TeCl4
O3
CH3OH
ClO2-
ICl4-
COCl2
PCl6-
GaCl3
HCCH
ClF5
Chapter 5 Solutions
Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
Ch. 5 - What is electronegativity? What are the periodic...Ch. 5 - Explain the difference between a pure covalent...Ch. 5 - What is meant by the percent ionic character of a...Ch. 5 - Prob. 4ECh. 5 - What is the magnitude of the dipole moment formed...Ch. 5 - What is the basic procedure for writing a covalent...Ch. 5 - How do you determine the number of electrons that...Ch. 5 - What are resonance structures? What is a resonance...Ch. 5 - Prob. 9ECh. 5 - Prob. 10E
Ch. 5 - Prob. 11ECh. 5 - Prob. 12ECh. 5 - What is bond energy?Ch. 5 - Give some examples of some typical bond lengths....Ch. 5 - Why is molecular geometry important? Cite some...Ch. 5 - According to VSEPR theory, what determines the...Ch. 5 - Name and draw the five basic electron geometries,...Ch. 5 - Explain the difference between electron geometry...Ch. 5 - List the correct electron and molecular geometries...Ch. 5 - How do you apply VSEPR theory to predict the shape...Ch. 5 - How do you determine if a molecule is polar?Ch. 5 - Why is polarity a key connection between the...Ch. 5 - Prob. 23ECh. 5 - Determine if a bond between each pair of atoms...Ch. 5 - Prob. 25ECh. 5 - Draw the Lewis structure for BrF with an arrow...Ch. 5 - Prob. 27ECh. 5 - Write the Lewis structure for each molecule. NF3...Ch. 5 - Prob. 29ECh. 5 - Write the Lewis structure for each molecule. CH2O...Ch. 5 - Prob. 31ECh. 5 - Prob. 32ECh. 5 - Write the Lewis structure for each molecule or ion...Ch. 5 - Prob. 34ECh. 5 - Write a Lewis structure that obeys the octet rule...Ch. 5 - Prob. 36ECh. 5 - Use formal charge to determine which Lewis...Ch. 5 - Prob. 38ECh. 5 - How important is this resonance structure to the...Ch. 5 - Prob. 40ECh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - Determine the formal charges of the atoms shown in...Ch. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - Write the Lewis structure for each molecule (octet...Ch. 5 - Prob. 47ECh. 5 - Write Lewis structures for each molecule or ion....Ch. 5 - Prob. 49ECh. 5 - Write Lewis structures for each molecule or ion....Ch. 5 - List these compounds in order of increasing...Ch. 5 - Which of these compounds has the stronger...Ch. 5 - A molecule with the formula AB3 has a trigonal...Ch. 5 - A molecule with the formula AB3 has a trigonal...Ch. 5 - For each molecular geometry shown here, list the...Ch. 5 - For each molecular geometry shown here, list the...Ch. 5 - Determine the electron geometry, molecular...Ch. 5 - Determine the electron geometry, molecular...Ch. 5 - Which species has the smaller bond angle, H3O+ or...Ch. 5 - Which species has the smaller bond angle; C1O4- or...Ch. 5 - Determine the molecular geometry and draw each...Ch. 5 - Determine the molecular geometry and draw each...Ch. 5 - Determine the molecular geometry about each...Ch. 5 - Prob. 64ECh. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - Prob. 67ECh. 5 - Determine the geometry about each interior atom in...Ch. 5 - Explain why CO2 and CCl4 are both nonpolar even...Ch. 5 - CH3F is a polar molecule, even though the...Ch. 5 - Determine whether each molecule in Exercise 57 is...Ch. 5 - Prob. 72ECh. 5 - Determine whether each molecule or ion is polar or...Ch. 5 - Determine whether each molecule is polar or...Ch. 5 - Each compound contains both ionic and covalent...Ch. 5 - Prob. 76ECh. 5 - Carbon ring structures are common in organic...Ch. 5 - Prob. 78ECh. 5 - Prob. 79ECh. 5 - Diazomethane is a highly poisonous, explosive...Ch. 5 - Prob. 81ECh. 5 - Phosgene (Cl2CO) is a poisonous gas that was used...Ch. 5 - The cyanate ion (OCN-) and the fulminate ion...Ch. 5 - Prob. 84ECh. 5 - Prob. 85ECh. 5 - Prob. 86ECh. 5 - Prob. 87ECh. 5 - Prob. 88ECh. 5 - Prob. 89ECh. 5 - Free radicals are important in many...Ch. 5 - A compound composed of only carbon and hydrogen is...Ch. 5 - A compound composed of only carbon and chlorine is...Ch. 5 - Prob. 93ECh. 5 - The genetic code is based on four different bases...Ch. 5 - Prob. 95ECh. 5 - Prob. 96ECh. 5 - Prob. 97ECh. 5 - A 0.167-g sample of an unknown compound contains...Ch. 5 - Use the dipole moments of HF and HCI (given at the...Ch. 5 - One form of phosphorus exists as P4 molecules....Ch. 5 - A compound has the formula C8H8 and does not...Ch. 5 - Draw the Lewis structure for acetamide (CH3CONH2),...Ch. 5 - Prob. 103ECh. 5 - In the very first chapter of this book, we...Ch. 5 - Which statement best captures the fundamental idea...Ch. 5 - Prob. 106ECh. 5 - Have each member of your group represent an atom...Ch. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Pass a piece of paper around the group and ask...Ch. 5 - Prob. 112ECh. 5 - At least two different numbers of electron groups...Ch. 5 - Prob. 114ECh. 5 - The VSEPR model is useful in predicting bond...Ch. 5 - Which set of elements is arranged in order of...Ch. 5 - Prob. 2SAQCh. 5 - Which pair of atoms forms the most polar bond? C...Ch. 5 - Which pair of atoms forms a nonpolar covalent...Ch. 5 - Prob. 5SAQCh. 5 - Prob. 6SAQCh. 5 - Prob. 7SAQCh. 5 - Prob. 8SAQCh. 5 - Prob. 9SAQCh. 5 - Prob. 10SAQCh. 5 - Prob. 11SAQCh. 5 - Predict the relative bond angles in BF3 and SO2Ch. 5 - Predict the molecular geometry about N in the...Ch. 5 - Which molecule is polar?
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Classify each of the following statements as true or false: a Molecular geometry around an atom may or may not be the same as electron-pair geometry around the atom. b Electron pair geometry is the direct effect of molecular geometry. c If the geometry of a molecule is linear, the molecule must have at least one double bond. d A molecule with a double bond cannot have trigonal pyramidal geometry around the double bonded atom. e A CO2 molecule is linear, but an SO2 molecule is bent. f A molecule is polar if it contains polar bonds. g A molecule with a central atom that has one lone pair of electrons is always polar. h A molecule with a central atom that has two lone pairs and two bonded pairs of electrons is always polar. i Carbon atoms normally form four bonds. j Hydrogen atoms never form double bonds.arrow_forwardIndicate whether each of the following molecules is polar or nonpolar. The molecular geometry is given in parentheses. a. NF3 (trigonal pyramidal with N at the apex) b. NF2Cl (trigonal pyramidal with N at the apex) c. CS2 (linear with C in the center position) d. CHCl3 (tetrahedral with C in the center position)arrow_forwardDetermine the geometry about interior atom in molecule and draw the molecule. (Skeletal structure is indicated in parentheses.) CH3CO2CH3 (H3CCOOCH3 both O atoms attached to second C)arrow_forward
- Determine the geometry about interior atom in molecule and draw the molecule. (Skeletal structure is indicated in parentheses.) CH3OH (H3COH)arrow_forwardUsing the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter how complex. Cicutoxin is a poisonous compound isolated from water hemlock, a highly toxic plant that grows in temperate regions in North America. Predict the geometry around the highlighted atoms in cicutoxin.arrow_forwardDetermine the molecular geometry about each interior atom and draw each molecule. (Skeletal structure is indicated in parentheses.)a. C2H2 (HCCH) b. C2H4 (H2CCH2)c. C2H6 (H3CCH3)arrow_forward
- Determine the geometry about each interior atom in each molecule and sketch the molecule. (Skeletal structure is indicated in parentheses.)a. CH3OH (H3COH) b. CH3OCH3 (H3COCH3)c. H2O2 (HOOH)arrow_forwardA. Fluoromethane B. Methanol C. Chloromethane D. Water 1. Which molecule has the highest dipole moment? 2. Which molecule has the greatest bond angle relative to the electronegative atom? 3. Which molecule has the most optimal bond angle? 4. Which molecule is the most polar? 5. Which molecule contains the most electronegative atom?arrow_forwardDetermine the geometry about each interior atom in each molecule and sketch the molecule. (Skeletal structure is indicated in parentheses.)a. CH3NH2 (H3CNH2)b. CH3CO2CH3 (H3CCOOCH3 One O atom attached to 2nd C atom; the other O atom is bonded to the 2nd and 3rd C atom)c. NH2CO2H (H2NCOOH both O atoms attached to C)arrow_forward
- Which molecule is correctly paired with its VSPR shape? Group of answer choices PI3, trigonal planar CBr4, tetrahedral OF2, linear SiS2, bentarrow_forwardPlease draw the original Lewis structure then redraw the diagram in its molecular geometry and please state the molecular geometry of the elements down below. (NH2Cl) the last thing is Chlorinearrow_forwardFor each of the following molecules, draw the best Lewis structure; determine whether the bonds are polar or nonpolar; determine the shape of the molecule; determine whether the molecule is polar or nonpolar; determine the hybridization around the central atom. (i) IF3 (ii) PCl3 (iii) SO3arrow_forward
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