ORGANIC CHEMISTRY (LL)-W/MOD.MASTERING.
8th Edition
ISBN: 9780134466712
Author: Bruice
Publisher: PEARSON
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Chapter 5.11, Problem 34P
a. Which reaction has a greater equilibrium constant: one with a rate constant of 1 × 10–3 sec–1 for the forward reaction and a rate constant of 1 × 10–5 sec–1 for the reverse reaction, or one with a rate constant of 1 × 10–2sec–1 for the forward reaction and a rate constant of 1 × 10–3sec–1 for the reverse reaction?
b. If both reactions start with a reactant concentration of 1.0 M, which reaction will form the most product in a given period of time?
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a. Which reaction has a greater equilibrium constant: one with a rate constant of 1 * 10-3 sec-1 for the forward reaction and a rate constant of 1 * 10-5 sec-1 for the reverse reaction, or one with a rate constant of 1 * 10-2 sec-1 for the forward reaction and a rate constant of 1 * 10-3 sec-1 for the reverse reaction? b. If both reactions start with a reactant concentration of 1.0 M, which reaction will form the most product when the reactions have reached equilibrium?
Which reaction has a greater equilibrium constant: one with a rate constant of 1x10-3 sec-1 for the forward reaction and a rate constant of 1 x 10-5 sec-1 for the reverse reaction, or one with a rate constant of 1 x 10-2 sec-1 for the forward reaction and a rate constant of 1 x 10-3 sec-1 for the reverse reaction?
The equilibrium constant for an isomerization reaction is 6.2x1013. Which of the following statements is/are true?
The product concentration is much larger than the reactant concentration
The product concentration is much smaller than the reactant concentration
The rate constant for the forward reaction is much larger than the rate constant for the back reaction
The rate constant for the forward reaction is much smaller than the rate constant for the back reaction
The rate of the forward reaction is much larger than the rate of the back reaction
The rate of the forward reaction is much smaller than the rate of the back reaction
Chapter 5 Solutions
ORGANIC CHEMISTRY (LL)-W/MOD.MASTERING.
Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4PCh. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6PCh. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8PCh. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12PCh. 5.5 - Prob. 13P
Ch. 5.5 - Prob. 14PCh. 5.5 - Prob. 16PCh. 5.5 - Prob. 17PCh. 5.6 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.6 - a. Calculate the percentage of isopropylcylohexane...Ch. 5.6 - a. for which reaction in each set will S be more...Ch. 5.6 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.8 - Prob. 23PCh. 5.9 - Prob. 24PCh. 5.9 - How many different alkenes can be hydrogenated to...Ch. 5.9 - The same alkane is obtained from the catalytic...Ch. 5.9 - Prob. 27PCh. 5.9 - Rank the following compounds from most stable to...Ch. 5.10 - Prob. 29PCh. 5.10 - Prob. 30PCh. 5.11 - The rate constant for a reaction can be increased...Ch. 5.11 - Prob. 33PCh. 5.11 - a. Which reaction has a greater equilibrium...Ch. 5.12 - Draw a reaction coordinate diagram for a two-step...Ch. 5.12 - a. Which step in the reaction coordinate diagram...Ch. 5.12 - Draw a reaction coordinate diagram for the...Ch. 5.13 - Prob. 38PCh. 5 - What is each compounds systematic name?Ch. 5 - Prob. 40PCh. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Name the following:Ch. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 58PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - Prob. 60PCh. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 65PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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