Concept explainers
Which of the following choices represents the molar volume of an ideal gas at 25 °C and 1.5 atm?
a.
b.
c.
d.
e.
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Selected Solutions Manual For General Chemistry: Principles And Modern Applications
- 5-107 If 60.0 g of NH3 occupies 35.1 L under a pressure of 77.2 in. Hg, what is the temperature of the gas, in °C?arrow_forwardA 1.000-g sample of an unknown gas at 0C gives the following data: P(atm) V (L) 0.2500 3.1908 0.5000 1.5928 0.7500 1.0601 1.0000 0.7930 Use these data to calculate the value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). Plot the apparent molar masses against pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?arrow_forwardWhile resting, the average 70-kg human male consumes 14 L of pure O2 per hour at 25 C and 100 kPa. How many moles of 02 are consumed by a 70 kg man while resting for 1.0 h?arrow_forward
- 5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.arrow_forwardHelium gas, He, at 22C and 1.00 atm occupied a vessel whose volume was 2.54 L. What volume would this gas occupy if it were cooled to liquid-nitrogen temperature (197C)?arrow_forwardConsider the following unbalanced chemical equation: ^Sfr) + O2(g) —? Cu2O(s) + SO2(g) What volume of oxygen gas, measured at 27.5 °C and 0.998 atm. is required to react with 25 g of copper!I) sulfide? What volume of sulfur dioxide gas is produced under the same conditions?arrow_forward
- Consider the following unbalanced chemical equation: 6H12O6(s) + O2(g) -> CO,(g) + H2O(g) What volume of oxygen gas. measured at 28 °C and 0.976 atm. is needed to react with 5.00 g of C*H|2O6? What volume of each product is produced under the same conditions?arrow_forwardCalculate the molar volume of ethane at 1.00 atm and 0C and at 10.0 atm and 0C, using the van der Waals equation. The van der Waals constants are given in Table 5.7. To simplify, note that the term n2a/V2 is small compared with P. Hence, it may be approximated with negligible error by substituting nRT/P from the ideal gas law for V in this term. Then the van der Waals equation can be solved for the volume. Compare the results with the values predicted by the ideal gas law.arrow_forward5-46 Calculate the molar mass of a gas if 3.30 g of the gas occupies 660. mL. at 735 mm Hg and 27°C.arrow_forward
- Phosgene is a highly toxic gas made up of carbon, oxygen, and chlorine atoms. Its density at 1.05 atm and 25C is 4.24 g/L. (a) What is the molar mass of phosgene? (b) Phosgene is made up of 12.1% C, 16.2% O, and 71.7% Cl. What is the molecular formula of phosgene?arrow_forwardConsider a 5.00-L tank containing 325 g of H2O at a temperature of 275 C. (a) Calculate the pressure in the tank using both the ideal gas law and the van der Waals equation. (b) Which correction term, a(n/V)2 or bn, has the greatest influence on the pressure of this system?arrow_forward5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.arrow_forward
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