(a)
Interpretation:
The species from the given pairs with greater value of Vander Waal constant ‘a’ and ‘b’ needs to be determined.
Concept introduction:
The gases cannot behave ideally at all values of temperature and pressure.Therefore,the Vander Waal equation is introduced to explain the volume change and intermolecular force of attraction between gas particles.
Vander Waal constant ‘a’ indicates the intermolecular force of attraction between gas particles whereas ‘b’ indicates the volume correction of the molecule.
(b)
Interpretation:
The species from the given pairs with greater value of Vander Waal constant ‘a’ and ‘b’ needs to be determined.
Concept introduction:
The gases cannot behave ideally at all values of temperature and pressure. Therefore,the Vander Waal equation is introduced to explain the volume change and intermolecular force of attraction between gas particles.
Vander Waal constant ‘a’ indicates the intermolecular force of attraction between gas particles whereas ‘b’ indicates the volume correction of the molecule.
(c)
Interpretation:
The species from the given pairs with greater value of Vander Waal constant ‘a’ and ‘b’ needs to be determined.
Concept introduction:
The gases cannot behave ideally at all values of temperature and pressure therefore the Vander Waal equation is introduced to explain the volume change and intermolecular force of attraction between gas particles.
Vander Waal constant ‘a’ indicates the intermolecular force of attraction between gas particles whereas ‘b’ indicates the volume correction of the molecule.
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GENERAL CHEMISTRY-SOLUTIONS MANUAL
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