Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Textbook Question
Chapter 6, Problem 23E
up an example (not appearing in this ChemActivity) of a pair of molecules that are a)constitutional isomers, b) conformers. c) configurational stereoisomers.
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Which of the following conformers has the highest energy (the least stable)?Justify your choice
a. Draw the lowest energy conformation for the compound shown in the image.
b. Draw the complete structural formula of the following compound: cis-1-bromo-3-chlorocyclohexane.
Classify the pairs of molecules as not the same molecule, structural isomers, diastereomers,
enantiomers or identical. Circle any molecules that are not achiral
(a)
(b)
(c)
Br...
H CI
H
H
Br H
H3C
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Br
H Br
CI
I I
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Chapter 6 Solutions
Custom eBook for Organic Chemistry
Ch. 6 - Prob. 1CTQCh. 6 - Prob. 2CTQCh. 6 - Prob. 4CTQCh. 6 - Prob. 5CTQCh. 6 - Complete this graph of relative potential energy...Ch. 6 - Prob. 7CTQCh. 6 - Prob. 8CTQCh. 6 - Prob. 9CTQCh. 6 - Consider the Newman projection below. a. Draw a...Ch. 6 - Draw a Newman projection showing the lowest P.E....
Ch. 6 - Prob. 12CTQCh. 6 - Prob. 13CTQCh. 6 - In skeletal representations the hydrogens are not...Ch. 6 - Prob. 15CTQCh. 6 - Prob. 16CTQCh. 6 - Prob. 17CTQCh. 6 - Prob. 19CTQCh. 6 - Prob. 20CTQCh. 6 - Prob. 21CTQCh. 6 - Prob. 22CTQCh. 6 - Prob. 23CTQCh. 6 - Draw a constitutional isomer of pentane,...Ch. 6 - How many H’s are lost from the molecular formula...Ch. 6 - How many ifs are lost from the molecular formula...Ch. 6 - Prob. 27CTQCh. 6 - What is the degree of unsaturation for the example...Ch. 6 - Without counting hydrogens, determine which one of...Ch. 6 - Determine the degree of unsaturation (and draw a...Ch. 6 - a model of each molecule shown above: Is the...Ch. 6 - Prob. 32CTQCh. 6 - Prob. 33CTQCh. 6 - Label each double bond E, Z, or neither. (It may...Ch. 6 - Prob. 35CTQCh. 6 - Prob. 36CTQCh. 6 - Indicate the relationship between each pair....Ch. 6 - Prob. 38CTQCh. 6 - Prob. 1ECh. 6 - Prob. 2ECh. 6 - Using your model of butane (CH3CH2CH2CH3) ,...Ch. 6 - Consider the molecule 1-bromo-2-methylbutane. C3...Ch. 6 - Prob. 5ECh. 6 - Prob. 8ECh. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - Prob. 13ECh. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Double bonds do not rotate freely under normal...Ch. 6 - up an example (not appearing in this ChemActivity)...Ch. 6 - Prob. 24ECh. 6 - Prob. 25E
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- The energy difference between a tert-butyl group going from equatorial to axial in a cyclohexane is 18.3 kJ/mol. When two of the carbon atoms are replaced with oxygen atoms (molecule B) the energy difference between the two chair conformations drops to 5.9 kJ/mol. Explain this difference. (Hint: Consider what makes putting groups axial unfavorable).arrow_forwardDraw and name a constitutional isomer of C10H22 that has two stereocenters and is named an “ethyl ….hexane”.arrow_forward(b) Classify the following two pairs of structures as conformational or configurational isomers. Explain your answer. and HO, OH il. and ноarrow_forward
- Consider 1,2-dimethylcyclohexane.Q: Draw the two possible chair conformations for the trans isomer. Whichconformation, if either, is more stable?arrow_forwardQUESTION 3 (a) Draw the two conformations of ethane which has an energy minimum and energy maximum using the Newman projection. Explain why one conformation is lower in energy than the other.arrow_forwardWhat is the relationship for the following pairs of compounds. The options include constitutional isomers, not isomers, enantiomers, conformers, identical, resonance structures.arrow_forward
- Consider 1,2-dimethylcyclohexane.Q: Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?arrow_forwardFor the following two pairs of molecules, (1) Draw out the chair conformation for each molecule, flip the ring if it is possible. (2) Compare both molecules to circle out which one is more stable. (3) Identify their relationship as: constitutional isomer, conformational isomer, stereoisomer or identical. (4) Find all the chiral center on each molecule and label them. VS. ****arrow_forward1: Draw the chain conformer of... 1a. Cyclohexane, label all the axial and equatorial hydrogens 1b. The most stable conformer of ethylcyclohexane 1c. The most sable conformer of trans-1-tert-butyl-3-methylcyclohexanearrow_forward
- Using your knowledge of (and the definition of) cis and trans isomers and the following fact(s) about Cis/Trans Isomers please answer the following: (FACT(S): With multiple double bonds in a compound the TRANS-TRANS configuration is the most stable conformation. With multiple double bonds in a compound the CIS-CIS configuration is the least stable conformation.) Which structure is the least stable based on the information given?arrow_forwardAmong the figure, (a) what is the most stable conformation of n-pentane? (b) gauche conformation of butane and (c) least stable conformation of butanearrow_forward(a) Using Newman projections, draw all staggered and eclipsed conformations that result from rotation around the bond highlighted in red in each molecule; (b) draw a graph of energy versus dihedral angle for rotation around this bond.arrow_forward
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