ORGANIC CHEMISTRY LL PRINT UPGRADE
4th Edition
ISBN: 9781119810643
Author: Klein
Publisher: WILEY
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Chapter 6, Problem 56IP
(a)
Interpretation Introduction
Interpretation: The migrating carbon atom and curved arrow for migration are interpreted for the given carbocation rearrangement.
Concept introduction: The chemical transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. A carbocation is one of the intermediates that can rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary > Secondary > Primary
(b)
Interpretation Introduction
Interpretation: The more stability of carbocation (2) compared to (1) is interpreted for the given carbocation rearrangement.
Concept introduction: The chemical transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. A carbocation is one of the intermediates that can rearrange to form a more stable carbocation. The stability order of carbocation is:
Tertiary > Secondary > Primary
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Students have asked these similar questions
6:08 PM Wed Apr 5
a) Identify the alkyl halide (i.e., an alkane chain attached to a halogen) as primary, secondary,
or tertiary.
b) Draw the carbocation upon spontaneous dissociation between the C and Br atom.
c) Identify the carbocation as primary, secondary, or tertiary.
d) Is rearrangement possible, if yes, then draw that outcome and label the carbocation type (e.g.,
primary, secondary, or tertiary etc.).
Br
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7. a) Add all lone pairs for all of the molecules below (both sides of arrow)!
b Draw the mechanism arrows from starting materials to show the formation of the products
H.
O-H
Br
Br
bn
6. a.) Classify the following carbocations (1°, 2°, or 3°).
b.) Encircle the carbocation/s that can rearrange to a more stable structure.
smib-t.-S)
CH3
CH3
CH3 CH2 CH2
CHz-C+
CH3
Chapter 6 Solutions
ORGANIC CHEMISTRY LL PRINT UPGRADE
Ch. 6.1 - Prob. 1LTSCh. 6.1 - Prob. 1PTSCh. 6.1 - Prob. 2ATSCh. 6.2 - Prob. 3CCCh. 6.3 - Prob. 4CCCh. 6.3 - Prob. 5CCCh. 6.4 - Prob. 6CCCh. 6.6 - Prob. 7CCCh. 6.7 - Prob. 2LTSCh. 6.7 - Prob. 8PTS
Ch. 6.7 - Prob. 9PTSCh. 6.7 - Prob. 10ATSCh. 6.8 - Prob. 3LTSCh. 6.8 - Prob. 11PTSCh. 6.8 - Prob. 12ATSCh. 6.9 - Prob. 4LTSCh. 6.9 - Prob. 13PTSCh. 6.9 - Prob. 14ATSCh. 6.10 - Prob. 5LTSCh. 6.10 - Prob. 15PTSCh. 6.10 - Prob. 16ATSCh. 6.11 - Prob. 6LTSCh. 6.11 - Prob. 17PTSCh. 6.11 - Prob. 18ATSCh. 6 - Prob. 19PPCh. 6 - Prob. 20PPCh. 6 - Prob. 21PPCh. 6 - Prob. 22PPCh. 6 - Prob. 24PPCh. 6 - Prob. 25PPCh. 6 - Prob. 26PPCh. 6 - Prob. 27PPCh. 6 - Prob. 28PPCh. 6 - Prob. 29PPCh. 6 - Prob. 30PPCh. 6 - Prob. 31PPCh. 6 - Prob. 32PPCh. 6 - Prob. 33PPCh. 6 - Prob. 34PPCh. 6 - Prob. 35PPCh. 6 - Prob. 36PPCh. 6 - Prob. 37PPCh. 6 - Prob. 38PPCh. 6 - Prob. 39PPCh. 6 - Prob. 40PPCh. 6 - Prob. 41PPCh. 6 - Prob. 43ASPCh. 6 - Prob. 44ASPCh. 6 - Prob. 45ASPCh. 6 - Prob. 46ASPCh. 6 - Prob. 47ASPCh. 6 - Prob. 48ASPCh. 6 - Prob. 49ASPCh. 6 - Prob. 50IPCh. 6 - Prob. 51IPCh. 6 - Prob. 52IPCh. 6 - Prob. 53IPCh. 6 - Prob. 54IPCh. 6 - Prob. 55IPCh. 6 - Prob. 56IPCh. 6 - Prob. 57IPCh. 6 - Prob. 58IPCh. 6 - Prob. 59IPCh. 6 - Prob. 60IPCh. 6 - Prob. 61IPCh. 6 - Prob. 62CPCh. 6 - Prob. 64CP
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