Chemistry: The Molecular Science

5th Edition

ISBN: 9781285199047

Author: John W. Moore, Conrad L. Stanitski

Publisher: Cengage Learning

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Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.

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Textbook Question

Chapter 6.12, Problem 6.11PSP

Repeat Problem-Solving Example 6.11, but use N₂ instead of C₂.

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Chapter 6.11, Problem 2CE

Chapter 6.12, Problem 6.12PSP

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Chapter 6 Solutions

Chemistry: The Molecular Science

Ch. 6.2 - Write Lewis structures for (a) NF3, (b) N2H4, and...Ch. 6.3 - Prob. 6.1E Ch. 6.3 - Prob. 6.2PSP Ch. 6.4 - Prob. 6.2CE Ch. 6.4 - Write Lewis structures for (a) nitrosyl ion, NO+;...Ch. 6.5 - Prob. 6.4CE Ch. 6.5 - Prob. 6.5CE Ch. 6.5 - Prob. 6.4PSP Ch. 6.6 - Prob. 6.5PSP Ch. 6.6 - Use Equation 6.1 and values from Table 6.2 to...

Ch. 6.6 - Prob. 6.6CE Ch. 6.7 - Prob. 6.7PSP Ch. 6.7 - Prob. 6.7CE Ch. 6.8 - Prob. 6.8PSP Ch. 6.9 - Prob. 6.9PSP Ch. 6.9 - Prob. 6.9CE Ch. 6.10 - Prob. 6.10PSP Ch. 6.11 - Prob. 6.10E Ch. 6.11 - Prob. 6.11E Ch. 6.11 - Prob. 1CE Ch. 6.11 - Prob. 2CE Ch. 6.12 - Repeat Problem-Solving Example 6.11, but use N2...Ch. 6.12 - Use MO theory to predict the bond order and the...Ch. 6 - Prob. 1QRT Ch. 6 - Prob. 2QRT Ch. 6 - Prob. 3QRT Ch. 6 - Prob. 4QRT Ch. 6 - Prob. 5QRT Ch. 6 - Prob. 6QRT Ch. 6 - Which of these molecules have an odd number of...Ch. 6 - Prob. 8QRT Ch. 6 - Prob. 9QRT Ch. 6 - Prob. 10QRT Ch. 6 - Prob. 11QRT Ch. 6 - Prob. 12QRT Ch. 6 - Explain in your own words why the energy of two H...Ch. 6 - Prob. 14QRT Ch. 6 - Prob. 15QRT Ch. 6 - Prob. 16QRT Ch. 6 - Prob. 17QRT Ch. 6 - Prob. 18QRT Ch. 6 - Prob. 19QRT Ch. 6 - Write Lewis structures for tetracyanoethene,...Ch. 6 - Prob. 21QRT Ch. 6 - Prob. 22QRT Ch. 6 - Prob. 23QRT Ch. 6 - Prob. 24QRT Ch. 6 - Prob. 25QRT Ch. 6 - Prob. 26QRT Ch. 6 - Prob. 27QRT Ch. 6 - Prob. 28QRT Ch. 6 - Prob. 29QRT Ch. 6 - For each pair of bonds, predict which is the...Ch. 6 - Prob. 31QRT Ch. 6 - Prob. 32QRT Ch. 6 - Which bond requires more energy to break: the...Ch. 6 - Estimate ΔrH° for forming 2 mol ammonia from...Ch. 6 - Prob. 35QRT Ch. 6 - Light of appropriate wavelength can break chemical...Ch. 6 - Prob. 37QRT Ch. 6 - Prob. 38QRT Ch. 6 - Prob. 39QRT Ch. 6 - Acrolein is the starting material for certain...Ch. 6 - Prob. 41QRT Ch. 6 - Prob. 42QRT Ch. 6 - Write the correct Lewis structure and assign a...Ch. 6 - Prob. 44QRT Ch. 6 - Prob. 45QRT Ch. 6 - Two Lewis structures can be written for nitrosyl...Ch. 6 - Prob. 47QRT Ch. 6 - Prob. 48QRT Ch. 6 - Prob. 49QRT Ch. 6 - Prob. 50QRT Ch. 6 - Several Lewis structures can be written for...Ch. 6 - Prob. 52QRT Ch. 6 - Prob. 53QRT Ch. 6 - Prob. 54QRT Ch. 6 - Prob. 55QRT Ch. 6 - Draw resonance structures for each of these ions:...Ch. 6 - Three known isomers exist of N2CO, with the atoms...Ch. 6 - Write the Lewis structure for (a) BrF5 (b) IF5 (c)...Ch. 6 - Write the Lewis structure for BrF3 XeF4 Ch. 6 - Prob. 60QRT Ch. 6 - Prob. 61QRT Ch. 6 - Prob. 62QRT Ch. 6 - All carbon-to-carbon bond lengths are identical in...Ch. 6 - Prob. 64QRT Ch. 6 - Prob. 65QRT Ch. 6 - Prob. 66QRT Ch. 6 - Prob. 67QRT Ch. 6 - Prob. 68QRT Ch. 6 - Prob. 69QRT Ch. 6 - Prob. 70QRT Ch. 6 - Using just a periodic table (not a table of...Ch. 6 - The CBr bond length in CBr4 is 191 pm; the BrBr...Ch. 6 - Prob. 73QRT Ch. 6 - Acrylonitrile is the building block of the...Ch. 6 - Prob. 75QRT Ch. 6 - Write Lewis structures for (a) SCl2 (b) Cl3+ (c)...Ch. 6 - Prob. 77QRT Ch. 6 - Prob. 78QRT Ch. 6 - A student drew this incorrect Lewis structure for...Ch. 6 - This Lewis structure for SF5+ is drawn...Ch. 6 - Tribromide, Br3, and triiodide, I3, ions are often...Ch. 6 - Explain why nonmetal atoms in Period 3 and beyond...Ch. 6 - Prob. 83QRT Ch. 6 - Prob. 84QRT Ch. 6 - Prob. 85QRT Ch. 6 - Prob. 86QRT Ch. 6 - Which of these molecules is least likely to exist:...Ch. 6 - Write the Lewis structure for nitrosyl fluoride,...Ch. 6 - Prob. 91QRT Ch. 6 - Methylcyanoacrylate is the active ingredient in...Ch. 6 - Aspirin is made from salicylic acid, which has...Ch. 6 - Prob. 94QRT Ch. 6 - Prob. 95QRT Ch. 6 - Prob. 96QRT Ch. 6 - Prob. 97QRT Ch. 6 - Prob. 98QRT Ch. 6 - Nitrosyl azide, N4O, is a pale yellow solid first...Ch. 6 - Write the Lewis structures for (a) (Cl2PN)3 (b)...Ch. 6 - Nitrous oxide, N2O, is a linear molecule that has...Ch. 6 - The azide ion, N3, has three resonance hybrid...Ch. 6 - Hydrazoic acid, HN3, has three resonance hybrid...Ch. 6 - Prob. 104QRT Ch. 6 - Experimental evidence indicates the existence of...Ch. 6 - Prob. 106QRT Ch. 6 - Prob. 107QRT Ch. 6 - Pipeline, the active ingredient in black pepper,...Ch. 6 - Sulfur and oxygen form a series of 2 anions...Ch. 6 - Prob. 110QRT Ch. 6 - Prob. 111QRT Ch. 6 - Prob. 112QRT Ch. 6 - Prob. 113QRT Ch. 6 - Prob. 114QRT Ch. 6 - Prob. 115QRT Ch. 6 - Prob. 116QRT Ch. 6 - Prob. 117QRT Ch. 6 - Prob. 118QRT Ch. 6 - Prob. 6.ACP Ch. 6 - Prob. 6.BCP Ch. 6 - Prob. 6.CCP

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Repeat Problem-Solving Example 6.11, but use N 2 instead of C 2 .

Solution Summary: The author explains that the molecular orbital electron configuration, number of unpaired electrons, and the bond order of nitrogen molecule have to be determined.

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Chapter 6 Solutions