Introduction To Quantum Mechanics
Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 6.7, Problem 6.25P
To determine

Evaluate the expectation value of an electron in the hydrogen for the dipole moment pe.

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Solve the 3-dimensional harmonic oscillator for which V(r) = 1/2 mω2(x2 + y2 + z2), by the separation of variables in Cartesian coordinates.  Assume that the 1-D oscillator has eigenfunctions ψn(x) that have corresponding energy eigenvalues En = (n+1/2)ħω. What is the degeneracy of the 1st excited state of the oscillator?
A simple illustration of the variation method is provided by the hydrogen atom in the 1s state. Let us assume a form of the trial wave function ψ=e–br where b is a constant. For hydrogen atom, V=-e2/r, so the Hamiltonian operator is Ĥ=-h2/8π2m V2- e2/r.The energy depends on r for the 1s state of the hydrogen atom so the angular portion of the Laplacian can be omitted and replaced by the factor 4π after integration. Therefore, the radial portion of V2=1/r2 (∂/∂r) r2 ∂/∂r.  Solve the energy minimum of the hydrogen atom, E = -2π2 me4/h2.
If you double the width of a one-dimensional infinite potential well, (a) is the energy of the ground state of the trapped electron multiplied by 4, 2, , , or some other number? (b) Are the energies of the higher energy states multiplied by this factor or by some other factor, depending on their quantum number?
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