Concept explainers
(a)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(a)
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Answer to Problem 47PP
The systematic name of the given compound must be 2-chloropropane and the common name is isopropyl chloride.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with one substituent; chloro at C2 position. Thus, the systematic name of the given compound must be 2-chloropropane and the common name is isopropyl chloride.
(b)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(b)
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Answer to Problem 47PP
The systematic name of the given compound must be 2-bromo-2-methylpropane and the common name is tert-butyl bromide.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with two substituents: chloro and methyl at 2 positions. Thus, the systematic name of the given compound must be 2-bromo-2-methylpropane and the common name is tert-butyl bromide.
(c)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(c)
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Answer to Problem 47PP
The systematic name of the given compound must be 1-iodopropane and the common name is propyl iodide.
Explanation of Solution
In the given organic compound the parent longest chain contains 3 carbon atoms so the root word must be propane with one substituent; iodo at 1 position. Thus, the systematic name of the given compound must be 1-iodopropane and the common name is propyl iodide.
(d)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(d)
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Answer to Problem 47PP
The systematic name of the given compound must be (R)-2-bromobutane and the common name is (R)- sec-butyl bromide.
Explanation of Solution
In the given organic compound the parent longest chain contains 4 carbon atoms so the root word must be butane with one substituent; bromo at C2 position. Thus, the systematic name of the given compound must be (R)-2-bromobutane and the common name is (R)- sec-butyl bromide. The prefix (R) indicates the clockwise rotation of the groups bonded at the chiral C atom when arranged from 1 to 4 in the increasing order of their
(e)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(e)
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Answer to Problem 47PP
The systematic name of the given compound must be 1-chloro-2,2- dimethylpropane and common name is neopentyl chloride.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with three substituents as methyl and chloro at C1 and C2 position. Thus, the systematic name of the given compound must be 1-chloro-2,2- dimethylpropane and the common name is neopentyl chloride.
(f)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(f)
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Answer to Problem 47PP
The systematic name of the given compound must be 4-bromo-3,3-dimethyl-4-propylhaptane.
Explanation of Solution
In the given organic compound the parent longest chain contains 7 carbon atoms so the root word must be haptane with four substituents as propyl, methyl and bromo. Thus, the systematic name of the given compound must be 4-bromo-3,3-dimethyl-4-propylhaptane.
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Chapter 7 Solutions
ORGANIC CHEMISTRY 2-SEMESTER-ACCESS
- Give IUPAC names or provide the structures of each of the following compounds.arrow_forwardDraw the structures of the following compounds. (a) 1-isobutyl-4-isopropylcyclohexane; (b) tert-butylcyclopentane;(c) 3,3-diisopropyloctanearrow_forwardDraw the structural formula for each of the following compounds:(i) 3-methyl-5-(2,2-dimethylpropyl) nonane(ii) 1,2-dichloro-3-methylcyclohexanearrow_forward
- Organic Chemistry: Nomenclature for Alkyl Halides Give a systematic name for the following compound:arrow_forwardDraw the structures of the following compounds. (a) 1-chloro-1 isopropylcyclopentanearrow_forward(b) 3-Chloro-1,4-hexadiene (R), (Z) isomer name: (S), (Z) isomer name: (R), (E) isomer name: (S), (E) isomer name:arrow_forward
- Give the systematic (IUPAC) name for the following compounds, respectively. (If applicable, include whether it is a cis or a trans isomer in the name(s).arrow_forwardGive the IUAPC name of the following compounds.arrow_forwardDraw the structures for the following compounds.(a) 3-benzyl-4-bromohexane , 4,4-dimethylcyclohexene(b) trans-4,5-dibromohex-2-ene , cis-1,1-dibromo-2-ethyl-2,3-dimethylcyclobutanearrow_forward
- The structural analysis of compound Z provides spectroscopic data as shown below. By systematic analysis, determine the structure of the compound!arrow_forwardDraw the structural formulas of compounds A, C, D, E and F and draw the isomer of B, with the explaination on which one would be the major product and why.arrow_forwardArrange the following compounds in increasing order of their property as indicated :(i) CH3COCH3, C6H5COCH3, CH3CHO(reactivity towards nucleophilic addition reaction)(ii) Cl—CH2—COOH, F—CH2—COOH, CH3—COOH (acidic character)arrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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