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ORGANIC CHEMISTRY 2-SEMESTER-ACCESS
- F3C + CI OH CH3 N. CH3 KOH DMSO CH3 F3C Loss Tox H H F3C (Fluoxetine) CH3 CH3 H a. The rate of the reaction depends on both phenol and alkyl chloride. Is this an SN1 or an SN2 reaction? Draw the reaction mechanism below. Page 6 of 7 b. The physiologically active enantiomer of fluoxetine has (S) stereochemistry. Based on your answer in part (a), draw the correct stereochemistry of the alkyl chloride needed to produce this physiologically active (S)-Fluoxetinearrow_forwardWhat is the major product in the reaction below? B What type of reaction would take place? E1 (Zaitsev) Br I A B NaQEt major product C D [Select] ce ✓ E1 (Zaitsev) E2 (Zaitsev) od E2 (Hofmann) E1 (Hofmann)arrow_forwardDraw the substitution products for each of the following reactions; if the products can exist as stereoisomers, show what stereoisomers are obtained: a. (R)-2-bromopentane + CH3O- b. (R)-3-bromo-3-methylheptane + CH3OH c. benzyl chloride + CH3CH2OH d. allyl chloride + CH3OH e. 1-bromo-2-butene + CH3O- f. 1-bromo-2-butene + CH3OHarrow_forward
- What is the major product of the reaction below? H-Br 150 °C Br- Br Br Br A в Select one: а. D b. C с. В d. Aarrow_forward8. Rank in order of increasing nucleophilicity (starting with the weakest one) in polar aprotic solvent: Cr A SH™ CH3 OH B C Darrow_forwardWhich one is the product of the following reaction? Br CH₂C1 AICI3 A.m-Bromochlorobenzene B.o- Bromochlorobenzene and p- Bromochlorobenzene C.o-Bromotoluene and p-Bromotoluene D.m-Bromotoluenearrow_forward
- Which is expected to be the major product for the following reaction: Br₂, FeBr3 Hol H₂C O O O H₂C BrH₂C Br. H3C q O Br O H₂C محمد Br Q Oarrow_forwarda. Which is a stronger acid? a or b? NH2 NH3 b a b. If nitration is done on both of them, draw the structures of the products? c. Identify a,b,c, and d a CH3CH2CHO OzJZn/CH3COOH b+ C Ether d Li(CH3)2Cu/H3O* T T T Arial A 5 (18pt +T-= Path: p Words:0 QUESTION 12 a. How many different proton signals and carbon signals will be observed for the following compound in its proton NMR spectrum? Indicate the proton spin multiplicity? H3C. CH-O-C-CH2-CH H3C b. Predict the products of the reaction with acetaldehyde with the following reagents? a. NaBH4, then H30* b. Dess_Martin reagent c. Methylmagnesium bromide, then H30* d. (C6H5)3P=CH2arrow_forwardWhich reagent will convert an alcohol to a good leaving group and follow the stereochemistry shown below? OH LG Reagent O A. pyridine, SOCI2 O B. PB13 O C. HCI O D.CITS, pyridinearrow_forward
- What is the major product of the following reaction sequence? R = cyclohexyl. Br + Mg R2BH/NaO,H H2CrO4 O a. octan-3-one O b. octan-2-one c. octan-4-one d. octanal O e. octanoic acid Clear my choicearrow_forwardChoose the correct major product for the following reaction: Ent N A O A B H 1. LiAlH4 (XS) 2. H₂O B 3. O OH Cuto [H*] NaBH3CN HO с N I-Z H D Narrow_forwardSelect the correct product for the following transformation: Br. Br NaCN ? DMSO NC A B с D A 'Br Br. B CN NC. с CN CN Br. De Br D enatiomerarrow_forward
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