Theelementary steps depicting the mechanisms of each of the given reaction are to be written. Concept introduction: > The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism. > The E1 mechanism involves the formation of carbocations. > Thestability order of carbocation is methyl < primary < secondary < tertiary. > The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons. > The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Question

Want to see the full answer?

Answer 1

Question

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Write the inner sphere mechanism for the given reaction

Can you please help me and for a, b, and c, please give a brief explanation of the following rules. Thank you so much

Please provide a detailed mechanism for the following transformation. Also, show the appropriate curved arrows to rationalize the next step. The quality of the electron pushing counts.

Answer 2

Question

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Answer 6

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Answer 7

Chapter 7, Problem 53P

Interpretation Introduction

Interpretation:

Theelementary steps depicting the mechanisms of each of the given reaction are to be written.

Concept introduction:
>
The dehydration of secondary and tertiary alcohol proceeds through E1 mechanism.
>
The E1 mechanism involves the formation of carbocations.
>
Thestability order of carbocation is methyl < primary < secondary < tertiary.
>
The carbocation may be rearrangedbyshift of hydride oralkyl group of adjacent carbons.
>
The selection of hydride or alkyl group shift depends on the stability of the carbocation formed.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 7.1 - Name each of the following using IUPAC...Ch. 7.1 - Prob. 2P Ch. 7.2 - How many carbon atoms are sp2-hybridized in the...Ch. 7.3 - Prob. 4P Ch. 7.3 - Are cis-2-hexene and trans-3-hexene stereoisomers?...Ch. 7.4 - Prob. 6P Ch. 7.4 - Prob. 7P Ch. 7.4 - Give the IUPAC name of each of the compounds in...Ch. 7.5 - Arrange the following in order of increasing...Ch. 7.6 - Prob. 10P

Solution Summary: The author explains how the carbocation intermediate undergoes rearrangement by 1,2-methyl shift.

Concept explainers

Want to see the full answer?

Chapter 7 Solutions