The relative amounts of axial conformations in samples of methylcyclohexane and tert -butylcyclohexane are to be stated. Concept introduction: The conformation of cyclohexane is a type of 3 − D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

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Answer 1

Question

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

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(B) Draw two chair conformations of the following substituted cyclohexane and identify the most stable conformation. Clearly show the axial and equatorial bonds.

Which do you expect to be the more stable conformation of cis-1,3-dimethylcyclobutane, A or B? Why?

How the relative stability of the two conformations of any disubstituted cyclohexane can be analyzed ?

Answer 2

Question

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

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Answer 3

Question

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

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Answer 4

Question

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

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Answer 5

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

Answer 6

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

Answer 7

Chapter 7, Problem 7.3P

Interpretation Introduction

Interpretation:

The relative amounts of axial conformations in samples of methylcyclohexane and tert-butylcyclohexane are to be stated.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. The two positions are present in all the four conformations; equatorial position and axial position.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

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