EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 7, Problem 7.75AP
Interpretation Introduction

(a)

Interpretation:

The total number of stereochemical ways by which the two rings in a bridged bicyclic compound can be joined is to be stated.

Concept introduction:

A molecule which contains two rings joined together is known as bicyclic molecule. The compound in which the two rings share three or more than three atoms and the two bridgehead atoms are separated through a bridge possessing at least one atom is known as bridged bicyclic compound.

Interpretation Introduction

(b)

Interpretation:

Among the bridged bicyclic compounds, bicyclo[2.2.2]octane and bicyclo[25.25.25]heptaheptacontane, the compound that has the stereoisomers which are highly stable and can be isolated easily is to be stated.

Concept introduction:

A molecule which contains two rings joined together is known as bicyclic molecule. The compound in which the two rings share three or more than three atoms and the two bridgehead atoms are separated through a bridge possessing at least one atom is known as bridged bicyclic compound.

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Gg.53.
pls answer both
(a) Draw all other stereoisomers of the molecule , labelling meso forms (if any), and assign descriptors to chiral carbon atoms.   (b) Including molecule below, label pairs of enantiomers and pairs of diastereomers.   (c) If you were to distill a mixture of all the isomers, how many fractions could be obtained, and what is in each fraction?

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EBK ORGANIC CHEMISTRY

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